A chiral porous 3D metal-organic framework with an unprecedented 4-connected network topology

被引：63

作者：

Wu, CD ^{[1
]}

Lin, WB ^{[1
]}

机构：

[1] Univ N Carolina, Dept Chem, Chapel Hill, NC 27599 USA

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 29期

关键词：

D O I：

10.1039/b505916j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel homochiral 3D metal-organic framework [CdL2(H2O)(2)][ClO4](2)center dot 2DMF center dot 3EtOH center dot 5/3H(2)O, 1, (L = (R)- 6,6'-dichloro- 2,2'-diethoxy-1,1'-binaphthyl-4,4'-bipyridine) exhibits an unprecedented 4-connected network topology owing to the cis- configuration of the Cd coordination and possesses permanent porosity as demonstrated by TGA, XRPD, and CO2 adsorption isotherm studies.

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页码：3673 / 3675

页数：3

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