The occurrence of peptaibols and structurally related peptaibiotics in fungi and their mass spectrometric identification via diagnostic fragment ions

被引:100
|
作者
Degenkolb, T
Berg, A
Gams, W
Schlegel, B
Gräfe, U
机构
[1] Hans Knoll Inst Nat Prod Res, D-07745 Jena, Germany
[2] Cent Bur Schimmelcultures, NL-3584 CT Utrecht, Netherlands
关键词
peptaibols; lipopeptaibols; lipoaminopeptides peptaibiotics; fungicolous fungi; ESI-CID-MS/MS; CID-MS(n); b-type fragmentation;
D O I
10.1002/psc.497
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Peptaibols and related peptide antibiotics (peptaibiotics) display diagnostically useful fragmentation patterns during mass spectrometry (FAB-MS, ESI-CID-MS/MS and CID-MS(n)). The paper compiles fragmentation data of pseudo-molecular ions reported in the literature as a guide to the rational identification of recurrently isolated and new peptaibols and peptaibiotics. Taxonomic and ecological aspects of microorganisms producing peptaibols and peptaibiotics are discussed. Copyright (C) 2003 European Peptide Society and John Wiley Sons, Ltd.
引用
收藏
页码:666 / 678
页数:13
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