Two zinc and cadmium coordination polymers constructed with bis(4-(1H-imidazol-1-yl)phenyl)methanone and naphthalene-1,4-dicarboxylate ligands: synthesis and structural characterization

被引：3

作者：

Wang, Gao-Feng ^{[1
]}

Yang, Hai-Ying ^{[1
]}

Peng, De-Qun ^{[1
]}

Sun, Shu-Wen ^{[1
]}

机构：

[1] Yuncheng Univ, Dept Appl Chem, Yuncheng 044000, Peoples R China

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2022年 / 77卷 / 09期

关键词：

cadmium; carboxylate ligands; coordination polymers; N-donor ligands; topology; zinc; METAL-ORGANIC FRAMEWORKS; CRYSTAL-STRUCTURES; COMPLEXES;

D O I：

10.1515/znb-2022-0079

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two coordination polymers, [Zn-2(bipmo)(2)(1,4-nda)(2)]( n ) (1), {[Cd(bipmo)(1,4-nda)]center dot(H2O)]}( n ) (2), (bipmo = bis(4-(1H-imidazol-1-yl)phenyl)methanone, H-2(1,4-nda) = naphthalene-1,4-dicarboxylic acid), were synthesized under solvothermal conditions. The complexes have been characterized by elemental analyses, IR spectroscopy and single-crystal X-ray diffraction. Complex 1 possesses 3D 2-fold interpenetrating nets with the Schlafli symbol {6(5)center dot 8}. Complex 2 consists a 3D net with the Schlafli symbol {4(4)center dot 6(10)center dot 8}. The luminescent properties of complexes 1 and 2 have been investigated.

引用

页码：643 / 649

页数：7

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