Microporous pillared paddle-wheel frameworks based on mixed-ligand coordination of zinc ions

被引：424

作者：

Ma, BQ ^{[1
]}

Mulfort, KL ^{[1
]}

Hupp, JT ^{[1
]}

机构：

[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

来源：

INORGANIC CHEMISTRY | 2005年 / 44卷 / 14期

关键词：

D O I：

10.1021/ic050452i

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of Zn(NO3)(2)-6H(2)O, various dicarboxylic acids, and either 4,4'-bipyridine or N,N'-di(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide produces a family of anisotropic, mixed-ligand, open-framework compounds featuring paddle-wheel-type coordination of Zn(II) pairs in two dimensions and pyridyl ligand pillaring in the third. Despite 2-fold interpenetration, the compounds contain channels of molecular dimensions and several are permanently microporous, displaying high internal surface areas.

引用

收藏

页码：4912 / 4914

页数：3

相关论文

共 24 条

[1] Design, chirality, and flexibility in nanoporous molecule-based materials [J].

Bradshaw, D ;

Claridge, JB ;

Cussen, EJ ;

Prior, TJ ;

Rosseinsky, MJ .

ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (04) :273-282

[2] A novel class of interpenetrated 3-D network of a dimeric cupric-tetracarboxylate unit [J].

Dalai, S ;

Mukherjee, PS ;

Zangrando, E ;

Lloret, F ;

Chaudhuri, NR .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (06) :822-823

[3] Rhenium-based molecular rectangles as frameworks for ligand-centered mixed valency and optical electron transfer [J].

Dinolfo, PH ;

Williams, ME ;

Stern, CL ;

Hupp, JT .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (40) :12989-13001

[4] Microporous manganese formate: A simple metal-organic porous material with high framework stability and highly selective gas sorption properties [J].

Dybtsev, DN ;

Chun, H ;

Yoon, SH ;

Kim, D ;

Kim, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (01) :32-33

[5] Rigid and flexible: A highly porous metal-organic framework with unusual guest-dependent dynamic behavior [J].

Dybtsev, DN ;

Chun, H ;

Kim, K .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (38) :5033-5036

[6] Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage [J].

Eddaoudi, M ;

Kim, J ;

Rosi, N ;

Vodak, D ;

Wachter, J ;

O'Keeffe, M ;

Yaghi, OM .

SCIENCE, 2002, 295 (5554) :469-472

[7] PREPARATION, CLATHRATION ABILITY, AND CATALYSIS OF A 2-DIMENSIONAL SQUARE NETWORK MATERIAL COMPOSED OF CADMIUM(II) AND 4,4'-BIPYRIDINE [J].

FUJITA, M ;

KWON, YJ ;

WASHIZU, S ;

OGURA, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (03) :1151-1152

[8] Chiral porous coordination networks: rational design and applications in enantioselective processes [J].

Kesanli, B ;

Lin, WB .

COORDINATION CHEMISTRY REVIEWS, 2003, 246 (1-2) :305-326

[9] Functional porous coordination polymers [J].

Kitagawa, S ;

Kitaura, R ;

Noro, S .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (18) :2334-2375

[10] Rational design and crystal structure determination of a 3-D metal-organic jungle-gym-like open framework [J].

Kitaura, R ;

Iwahori, F ;

Matsuda, R ;

Kitagawa, S ;

Kubota, Y ;

Takata, M ;

Kobayashi, TC .

INORGANIC CHEMISTRY, 2004, 43 (21) :6522-6524