Microporous pillared paddle-wheel frameworks based on mixed-ligand coordination of zinc ions

被引：421
作者：
Ma, BQ [1 ]
Mulfort, KL [1 ]
Hupp, JT [1 ]
机构：
[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA
来源：
INORGANIC CHEMISTRY | 2005年 / 44卷 / 14期
关键词：
D O I：
10.1021/ic050452i
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of Zn(NO3)(2)-6H(2)O, various dicarboxylic acids, and either 4,4'-bipyridine or N,N'-di(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide produces a family of anisotropic, mixed-ligand, open-framework compounds featuring paddle-wheel-type coordination of Zn(II) pairs in two dimensions and pyridyl ligand pillaring in the third. Despite 2-fold interpenetration, the compounds contain channels of molecular dimensions and several are permanently microporous, displaying high internal surface areas.
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收藏
页码：4912 / 4914
页数：3
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