Recent Advances in Electrochemical Nitrogen Reduction Reaction to Ammonia from the Catalyst to the System

被引：33
作者：
Moon, Yong Hyun [1 ]
Kim, Na Yun [1 ]
Kim, Sung Min [1 ]
Jang, Youn Jeong [1 ,2 ]
机构：
[1] Hanyang Univ, Dept Chem Engn, 222 Wangsimni Ro, Seoul 04763, South Korea
[2] Hanyang Univ, Inst Nano Sci & Technol, 222 Wangsimni Ro, Seoul 04763, South Korea
来源：
CATALYSTS | 2022年 / 12卷 / 09期
关键词：
ammonia; nitrogen reduction reaction; electrocatalyst; system engineering; three-phase boundary; HYDROGEN-EVOLUTION-REACTION; SINGLE-ATOM CATALYSTS; CARBON-DIOXIDE; CO2; REDUCTION; N-2; ELECTROREDUCTION; ELECTROCATALYST; AMORPHIZATION; TEMPERATURE; SOLUBILITY;
D O I：
10.3390/catal12091015
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
As energy-related issues increase significantly, interest in ammonia (NH3) and its potential as a new eco-friendly fuel is increasing substantially. Accordingly, many studies have been conducted on electrochemical nitrogen reduction reaction (ENRR), which can produce ammonia in an environmentally friendly manner using nitrogen molecule (N-2) and water (H2O) in mild conditions. However, research is still at a standstill, showing low performances in faradaic efficiency (FE) and NH3 production rate due to the competitive reaction and insufficient three-phase boundary (TPB) of N-2(g)-catalyst(s)-H2O(l). Therefore, this review comprehensively describes the main challenges related to the ENRR and examines the strategies of catalyst design and TPB engineering that affect performances. Finally, a direction to further develop ENRR through perspective is provided.
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页数：19
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