Cu-ZSM-5: A biomimetic inorganic model for methane oxidation

被引：158

作者：

Vanelderen, Pieter ^{[2
]}

Hadt, Ryan G. ^{[1
]}

Smeets, Pieter J. ^{[1
,2
]}

Solomon, Edward I. ^{[1
]}

Schoonheydt, Robert A. ^{[2
]}

Sels, Bert F. ^{[2
]}

机构：

[1] Stanford Univ, Dept Chem, Stanford, CA 94305 USA

[2] Katholieke Univ Leuven, Ctr Surface Chem & Catalysis, B-3001 Heverlee, Belgium

来源：

JOURNAL OF CATALYSIS | 2011年 / 284卷 / 02期

关键词：

Zeolite; Cu-ZSM-5; Dioxygen activation; Dicopper(II)-oxo; Selective methane oxidation; Bio-inorganic mimicking; C-H activation; LAYERED DOUBLE HYDROXIDES; DINUCLEAR COPPER(II) COMPLEXES; EXCHANGED ZSM-5 ZEOLITES; X-RAY-ABSORPTION; O-O BOND; VANADIUM BROMOPEROXIDASE; SELECTIVE OXIDATION; NITROGEN MONOXIDE; ACTIVE-SITES; CU+ SITES;

D O I：

10.1016/j.jcat.2011.10.009

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The present work highlights recent advances in elucidating the methane oxidation mechanism of the inorganic Cu-ZSM-5 biomimic and in identifying the reactive intermediates that are involved. Such molecular understanding is important in view of upgrading abundantly available methane, but also to comprehend the working mechanism of genuine Cu-containing oxidation enzymes. (C) 2011 Elsevier Inc. All rights reserved.

引用

页码：157 / 164

页数：8

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