The C-N stretching band of methylamine

被引：12

作者：

Gulaczyk, Iwona ^{[1
]}

Kreglewski, Marek ^{[1
]}

Horneman, Veli-Matti ^{[2
]}

机构：

[1] Adam Mickiewicz Univ Poznan, Fac Chem, PL-60780 Poznan, Poland

[2] Univ Oulu, Dept Phys Sci, Oulu, Finland

来源：

JOURNAL OF MOLECULAR SPECTROSCOPY | 2011年 / 270卷 / 01期

关键词：

Methylamine; C-N stretching; High resolution infrared spectrum; Loomis-Wood diagram; Coriolis and Fermi resonances; ASSIGNMENTS; VIBRATION; SPECTRUM; AMINE; STATE;

D O I：

10.1016/j.jms.2011.09.003

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

For the first time the C-N stretching band of methylamine has been assigned in a high resolution spectrum in the region from 960 to 1200 cm(-1). Over 3500 transitions with a resolution of 0.001 cm(-1) for K from 0 to 12 have been assigned. A global fit has been made and the band center was determined at 1044.8134(33) cm(-1). Several branches of the C-N band are strongly perturbed through Fermi and Coriolis type resonances. The sources of the perturbations have been identified - the fourth torsional state 4 nu(15) and the combination state nu(9) + nu(15). An attempt to fit the observed transitions to a single state model based on the group theoretical formalism of Ohashi and Hougen [1] resulted in the standard deviation of 0.04 cm(-1). (C) 2011 Elsevier Inc. All rights reserved.

引用

页码：70 / 74

页数：5

共 50 条

[31] Raman spectral study of vibrational relaxation of the C≡N stretching band of acetonitrile and benzonitrile
Department of Spectroscopy, Indian Assoc. the Cultiv. of Sci., Calcutta-32, India
不详
J. Raman Spectrosc., 6 (457-461):
[32] The numbers of spanning trees of the cubic cycle C-N(3) and the quadruple cycle C-N(4)
Yong, XR
Talip
Acenjian
DISCRETE MATHEMATICS, 1997, 169 (1-3) : 293 - 298
[33] Theory of frequency fluctuation of intramolecular vibration in solution phase: Application to C-N stretching mode of organic compounds
Negishi, Naoki
Yokogawa, Daisuke
JOURNAL OF CHEMICAL PHYSICS, 2025, 162 (10):
[34] Cleavage of C-N bonds in guanidine derivatives and its relevance to efficient C-N bonds formation
Chang, Denghu
Zhu, Dan
Zou, Peng
Shi, Lei
TETRAHEDRON, 2015, 71 (11) : 1684 - 1693
[35] ELASTIC SCATTERING IN N-N, C-N, AND C-C SYSTEMS
SMITH, AM
STEIGERT, FE
PHYSICAL REVIEW, 1962, 125 (03): : 988 - &
[36] Photodissociation kinetics of C-n(+) clusters
Bouyer, R
Monchicourt, P
Perdrix, M
Pradel, P
Roussel, F
JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, 1997, 30 (01) : 135 - 149
[37] Analytic geometry on compacta in C-n
Poletsky, EA
MATHEMATISCHE ZEITSCHRIFT, 1996, 222 (03) : 407 - 424
[38] (C-N) INSERTION OF ISOCYANIDE IN AMINALS
ZINNER, G
MODERHAC.D
HEUER, W
CHEMIKER-ZEITUNG, 1974, 98 (02): : 112 - 113
[39] CATALYTIC ACTIVATION OF C-N BONDS
LAINE, RM
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1988, 196 : 191 - COLL
[40] C-N MIGRATION OF BENZOYL GROUP
ALEKSANDROVA, ML
IOFFE, DV
ZHURNAL ORGANICHESKOI KHIMII, 1975, 11 (05): : 1135 - 1136

← 1 2 3 4 5 →