Structural and 1H, 13C, 15N NMR spectroscopic studies of Pd(II) chloride organometallics with 2-phenylpyridine and ammonia, pyridine or its methyl derivatives

被引：13

作者：

Niedzielska, Dania ^{[1
]}

Pawlak, Tomasz ^{[2
]}

Wojtczak, Andrzej ^{[1
]}

Pazderski, Leszek ^{[1
]}

Szlyk, Edward ^{[1
]}

机构：

[1] Nicolaus Copernicus Univ Torun, Fac Chem, PL-87100 Torun, Poland

[2] Polish Acad Sci, Ctr Mol & Macromol Studies, PL-90363 Lodz, Poland

来源：

POLYHEDRON | 2015年 / 92卷

关键词：

Pd(II) organometallics; 2-Phenylpyridine; N-15; NMR; X-ray; NMR coordination shifts; LITHIUM-METALLOID EXCHANGE; C-H BONDS; COORDINATION SHIFTS; ELECTROCHEMICAL PROPERTIES; CYCLOMETALATED COMPLEXES; CRYSTAL-STRUCTURE; CYCLOPLATINATED COMPLEXES; 1,4-DIAZINE DERIVATIVES; LUMINESCENCE PROPERTIES; PLATINUM(II) COMPLEXES;

D O I：

10.1016/j.poly.2015.02.028

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Pd(II) chloride organometallics with 2-phenylpyridine and pyridines of general formula [Pd(2ppy*)LCl] (2ppy* = C(2')-deprotonated form of 2-phenylpyridine (2ppy), acting as N(1),C(2')-chelating ligand; L = NH3, pyridine, 2-, 3-, 4-methylpyridine, 2,3-, 2,4-, 2,6-, 3,5-dimethylpyridine, 2,4,6-trimethylpyridine) were studied by H-1, C-13 and N-15 NMR. H-1, C-13 and N-15 NMR coordination shifts (i.e. differences of chemical shifts for the same atom in the complex and ligand molecules) were discussed in relation to the molecular structures. Single crystal X-ray structure of trans(N,N)-[Pd(2ppy*)(2,4,6col)Cl] was solved. The analysis of 15N NMR coordination shifts for the whole series of the studied organometallics exhibited that all of them had an analogous trans(N,N) geometry. (C) 2015 Elsevier Ltd. All rights reserved.

引用

页码：41 / 51

页数：11

共 86 条

[1] Synthesis and reactivity towards carbon monoxide of an optically active endo five-membered ortho-cyclopalladated imine:: X-ray molecular structure of trans-(μ-Cl)2[Pd(κ2-C,N-(R)-C6H4-CH=N-CHMe-Ph)]2 [J].

Albert, Joan ;

D'Andrea, Lucia ;

Granell, Jaume ;

Tavera, Raquel ;

Font-Bardia, Merce ;

Solans, Xavier .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2007, 692 (14) :3070-3080

[2] Synthesis of Cyclopalladated Derivatives of (E)-N-Benzylidene-2-(2,6-dichlorophenyl)ethanamine and Their Reactivity towards Monodentate and Symmetric Bidentate Lewis Bases [J].

Albert, Joan ;

Bosque, Ramon ;

D'Andrea, Lucia ;

Granell, Jaume ;

Font-Bardia, Merce ;

Calvet, Teresa .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2011, (24) :3617-3631

[3]

[Anonymous], 1987, Annual Reports on NMR Spectroscopy, DOI DOI 10.1016/50066-4103(08)60290-2

[4]

[Anonymous], 2015, SPECTR DAT ORG COMP

[5]

[Anonymous], 2013, CAMBR STRUCT DAT VER

[6]

[Anonymous], CRYSALIS CCD171 RED1

[7] N-15 NMR-STUDY OF SOME PALLADIUM(II) AMMINE COMPLEXES [J].

APPLETON, TG ;

HALL, JR ;

RALPH, SF ;

THOMPSON, CSM .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1988, 41 (09) :1425-1432

[8] NC palladacycles in the Heck arylation of ethylene: Synthesis, structure and their reactivity [J].

Atla, Shashi B. ;

Kelkar, Ashutosh A. ;

Puranik, Vedavati G. ;

Bensch, Wolfgang ;

Chaudhari, Raghunath V. .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2009, 694 (05) :683-690

[9] Spectroscopic and electrochemical properties of mixed-ligand cyclopalladinized complexes of deprotonated forms of 2-(2-thienyl)pyridine and 2-phenylpyridine with 1,10-phenantroline and its 1,4-diazine derivatives [J].

Balashev, K. P. ;

Cerezova, E. A. ;

Ivanov, M. A. ;

Tkacheva, T. A. .

RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2006, 76 (07) :1150-1156

[10] Spectroscopic and electrochemical properties of mixed-ligand cycloplatinated complexes based on 2-(2-thienyl)pyridine and 2-phenylpyridine with 1,10-phenantroline and its 1,4-diazine derivatives [J].

Balashev, K. P. ;

Ivanov, M. A. ;

Taraskina, T. V. ;

Cherezova, E. A. .

RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2006, 76 (05) :781-790

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