How to get the desired reduction voltage in a single framework! Metallacarborane as an optimal probe for sequential voltage tuning

被引：24

作者：

Tarres, Marius ^{[1
]}

Arderiu, Victor S. ^{[1
]}

Zaulet, Adnana ^{[1
]}

Vinas, Clara ^{[1
]}

de Biani, Fabrizia Fabrizi ^{[2
]}

Teixidor, Francesc ^{[1
]}

机构：

[1] ICMAB CSIC, Inst Ciencia Mat Barcelona, E-08193 Bellaterra, Spain

[2] Univ Siena, Dipartimento Biotecnol Chim & Farm, I-53100 Siena, Italy

来源：

DALTON TRANSACTIONS | 2015年 / 44卷 / 26期

关键词：

ELECTROCHEMICAL PARAMETRIZATION; REDOX; BORON; METHYLATION; COUPLE;

D O I：

10.1039/c5dt01464f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An appealingly wide set of redox couples ranging from -1.74 to -0.35 V based on a metallabisdicarbollide derivative, [M(C2B9H11-I-y(y))(2)](-) (M = Co, Fe), each being distinguished from the former by near 0.15 V and all having the same structure have been demonstrated. The redox active methyl viologen moiety ([MV](2+)) has been used as a benchmark.

引用

页码：11690 / 11695

页数：6

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