Analyzing Brazilian Vehicle Documents for Authenticity by Easy Ambient Sonic-Spray Ionization Mass Spectrometry*

被引：19
作者：
Romao, Wanderson [1 ]
Vaz, Boniek G. [1 ]
Lalli, Priscila M. [1 ]
Bueno, Maria Izabel M. S. [2 ]
Correa, Deleon N. [1 ,3 ]
Telles, Virginia L. C. N. [3 ]
de Castro, Eustaquio V. R. [4 ]
Eberlin, Marcos N. [1 ]
机构：
[1] Univ Estadual Campinas, Inst Chem, Thomson Mass Spectrometry Lab, BR-13084971 Campinas, SP, Brazil
[2] Univ Estadual Campinas, Inst Chem, Xray Spect Grp, BR-13084971 Campinas, SP, Brazil
[3] Criminalist Inst Dr Octavio Eduardo de Brito Alva, BR-05507060 Sao Paulo, Brazil
[4] Univ Fed Espirito Santo, Dept Chem, BR-29060900 Vitoria, ES, Brazil
来源：
JOURNAL OF FORENSIC SCIENCES | 2012年 / 57卷 / 02期
基金：
巴西圣保罗研究基金会;
关键词：
forensic science; questioned documents; desorption; ionization techniques; ambient mass spectrometry; EASI-MS; Brazilian vehicle documents; DESORPTION ELECTROSPRAY-IONIZATION; BALLPOINT PEN INKS; THIN-LAYER-CHROMATOGRAPHY; INSTANTANEOUS TYPIFICATION; LIQUID-CHROMATOGRAPHY; RAMAN-SCATTERING; ECSTASY TABLETS; ELECTROPHORESIS; DIFFERENTIATION; BLACK;
D O I：
10.1111/j.1556-4029.2011.02005.x
中图分类号：
DF [法律]; D9 [法律]; R [医药、卫生];
学科分类号：
0301 ; 10 ;
摘要：
Using desorption/ionization techniques such as easy ambient sonic-spray ionization mass spectrometry (EASI-MS), it is possible to analyze documents of Brazilian vehicles for authenticity, providing a chemical profile directly from the surface of each document. A method for the detection of counterfeit documents is described, and the falsification procedure is elucidated. Forty authentic and counterfeit documents were analyzed by both positive and negative ion modes, EASI(+/-)-MS. EASI(+)-MS results identified the presence of (bis(2-ethylhexyl)phthalate plasticizer and of dihexadecyldimethylammonium biocide in both types of documents. For EASI(-)-MS results, the 4-octyloxybenzoic acid additive ([M + H]+: m/z 249) is present only in counterfeit documents. It was also found that counterfeit vehicle documents are produced via Laserjet printers. Desorption/ionization techniques, such as EASI-MS, offer therefore, an intelligent way to characterize the counterfeiting method.
引用
收藏
页码：539 / 543
页数：5
相关论文
共 31 条
  • [21] Liquid chromatography coupled to Venturi easy ambient sonic spray ionization mass spectrometry
    Campos Oliveira, Luan Felipe
    Tega, David Ulisses
    Eberlin, Marcos Nogueira
    Sussulini, Alessandra
    TALANTA, 2022, 238
  • [22] EASY AMBIENT SONIC-SPRAY IONIZATION MASS SPECTROMETRIC OF OLIVE OILS: QUALITY CONTROL AND CERTIFICATION OF GEOGRAPHICAL ORIGIN
    Riccio, Maria Francesca
    Sawaya, Alexandra C. H. F.
    Abdelnur, Patricia V.
    Saraiva, Sergio A.
    Haddad, Renato
    Eberlin, Marcos N.
    Catharino, Rodrigo R.
    ANALYTICAL LETTERS, 2011, 44 (08) : 1489 - 1497
  • [23] Ambient Mass Spectrometry Imaging: A Comparison of Desorption Ionization by Sonic Spray and Electrospray
    Janfelt, Christian
    Norgaard, Asger W.
    JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY, 2012, 23 (10) : 1670 - 1678
  • [24] TAG, DAG and FFA Profiles of Dry-Cured Ham by Easy Ambient Sonic-Spray Ionization Mass Spectrometry After Thermal Imprinting
    Fernandes, Gabriel D.
    Moreda, Wenceslao
    Barrera-Arellano, Daniel
    Ruiz, Guilherme C. N. Z.
    Ferreira, Pedro L.
    Eberlin, Marcos N.
    Alberici, Rosana M.
    JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY, 2014, 25 (09) : 1565 - 1570
  • [25] Characterization of anti-theft devices directly from the surface of banknotes via easy ambient sonic spray ionization mass spectrometry
    Schmidt, Eduardo Morgado
    Franco, Marcos Fernando
    Cuelbas, Claudio Jose
    Zacca, Jorge Jardim
    de Carvalho Rocha, Werickson Fortunato
    Borges, Rodrigo
    de Souza, Wanderley
    Helena Frankland Sawaya, Alexandra Christine
    Eberlin, Marcos Nogueira
    Correa, Deleon Nascimento
    SCIENCE & JUSTICE, 2015, 55 (05) : 285 - 290
  • [26] LSD and 9,10-dihydro-LSD Analyses in Street Drug Blotter Samples via Easy Ambient Sonic-Spray Ionization MassSpectrometry (EASI-MS)
    Romao, Wanderson
    Sabino, Bruno D.
    Bueno, Maria Izabel M. S.
    Vaz, Boniek G.
    Junior, Amadeu C.
    Maldaner, Adriano O.
    de Castro, Eustaquio V. R.
    Lordeiro, Rogerio A.
    Nascentes, Clesia C.
    Eberlin, Marcos N.
    Augusti, Rodinei
    JOURNAL OF FORENSIC SCIENCES, 2012, 57 (05) : 1307 - 1312
  • [27] Selective and sensitive analysis by reactive easy ambient sonic-spray ionization: Synergistic combination of non-polar spray solvent and dicationic ionic liquid
    Lv, Yueguang
    Bai, Hua
    He, Yujian
    Yang, Jingkui
    Ma, Qiang
    TALANTA, 2020, 215
  • [28] Frontal elution paper chromatography for ambient ionization mass spectrometry: analyzing powder samples
    Huang, Yun-Qing
    You, Jin-Qing
    Cheng, Yupeng
    Sun, Wenjian
    Ding, Li
    Feng, Yu-Qi
    ANALYTICAL METHODS, 2013, 5 (16) : 4105 - 4111
  • [29] More inclusive or selective ionization for mass spectrometry using obstructive sonic spray ionization and voltage polarity switching
    Chubatyi, Nicholas D.
    Wang, Tongwen
    McEwen, Charles N.
    RAPID COMMUNICATIONS IN MASS SPECTROMETRY, 2012, 26 (23) : 2763 - 2769
  • [30] Paper spray ionization mass spectrometry applied to forensic chemistry - drugs of abuse, inks and questioned documents
    Domingos, Eloilson
    de Carvalho, Thays C.
    Pereira, Igor
    Vasconcelos, Gessica A.
    Thompson, Christopher J.
    Augusti, Rodinei
    Rodrigues, Rayza R. T.
    Tose, Lilian V.
    Santos, Heloa
    Araujo, Joyce R.
    Vaz, Boniek G.
    Ramao, Wanderson
    ANALYTICAL METHODS, 2017, 9 (30) : 4400 - 4409
1234