Valorisation of macroalgae industrial by-product as filler in thermoplastic polymer composites

被引:16
作者
Bulota, Mindaugas [1 ]
Budtova, Tatiana [1 ]
机构
[1] PSL Res Univ, UMR CNRS 7635, CEMEF Ctr Mise Forme Mat, Mines ParisTech, BP 207,CS 10207, Sophia Antipolis, France
关键词
Biocomposite; Mechanical properties; Seaweed by-products; MECHANICAL-PROPERTIES; THERMAL-PROPERTIES; BEHAVIOR; SEAWEED; FIBERS; ALGAE; BIOCOMPOSITES; MORPHOLOGY; POLY(L-LACTIDE); NANOCOMPOSITES;
D O I
10.1016/j.compositesa.2016.07.010
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Poly(lactic acid) composites filled with algae industrial by-product were prepared using melt-mixing process at filler weight fractions of 20, 30 and 40 wt%. Algae by-products were after the extraction of alginate (AW) and mixed with diatomaceous earth (DE). The composition and morphology of both fillers were analysed. Composites' mechanical properties and thermal degradation were investigated as a function of filler type and content. The addition of DE-filler at 40 wt% resulted in the increase of Young's modulus by 20% compared to the neat PLA. The presence of small DE particles improved stress distribution and led to stronger composites as compared with AW-filled. Cold crystallization of PLA was induced by small algae particles. Thermal degradation of all composites started at lower temperatures compared with neat PLA. A glow-wire test was carried out to evaluate the effect of inorganic matter on the ignition of the material. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码:271 / 277
页数:7
相关论文
共 33 条
[1]   Thermal, mechanical, morphological, thermogravimetric, rheological and toxicological behavior of HDPE/seaweed residues composites [J].
Albano, C ;
Karam, A ;
Domínguez, N ;
Sánchez, Y ;
González, J ;
Aguirre, O ;
Cataño, L .
COMPOSITE STRUCTURES, 2005, 71 (3-4) :282-288
[2]  
[Anonymous], 1979, CHEM SILICA SOLUBILI
[3]   Poly-(ε-Caprolactone) (PCL) and Poly(Hydroxy-Butyrate) (PHB) Blends Containing Seaweed Fibers: Morphology and Thermal-Mechanical Properties [J].
Barghini, Arianna ;
Ivanova, Vassilka I. ;
Imam, Syed H. ;
Chiellini, Emo .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2010, 48 (23) :5282-5288
[4]   PLA/algae composites: Morphology and mechanical properties [J].
Bulota, Mindaugas ;
Budtova, Tatiana .
COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING, 2015, 73 :109-115
[5]   Effect of gamma irradiation on mechanical, thermal and rheological behavior of HDPE filled with seaweed residues [J].
Cataño, L ;
Albano, C ;
Karam, A ;
Domínguez, N ;
Sánchez, Y ;
González, J .
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 2005, 236 :348-353
[6]   Mechanical and thermal properties of chicken feather fiber/PLA green composites [J].
Cheng, Sha ;
Lau, Kin-tak ;
Liu, Tao ;
Zhao, Yongqing ;
Lam, Pou-Man ;
Yin, Yansheng .
COMPOSITES PART B-ENGINEERING, 2009, 40 (07) :650-654
[7]   Composite films based on biorelated agro-industrial waste and poly(vinyl alcohol). preparation and mechanical properties characterization [J].
Chiellini, E ;
Cinelli, P ;
Imam, SH ;
Mao, L .
BIOMACROMOLECULES, 2001, 2 (03) :1029-1037
[8]   Biodegradable thermoplastic composites based on polyvinyl alcohol and algae [J].
Chiellini, Emo ;
Cinelli, Patrizia ;
Hieva, Vassilka I. ;
Martera, Martina .
BIOMACROMOLECULES, 2008, 9 (03) :1007-1013
[9]   Hybrid composites based on fibres of marine origin [J].
Chiellini, Emo ;
Cinelli, Patrizia ;
Ilieva, Vassilka Ivanova ;
Zimbardi, Francesco ;
Kanellopoulos, Nick ;
De Wilde, Bruno ;
Verstichel, Steven ;
Pipino, Andrea ;
Anders, Bernd ;
Sassi, Jean Francois .
INTERNATIONAL JOURNAL OF MATERIALS & PRODUCT TECHNOLOGY, 2009, 36 (1-4) :47-61
[10]  
Dodge JD, 1973, FINE STRUCTURE ALGAL