Cu2(BDC)2(BPY)-MOF: an efficient and reusable heterogeneous catalyst for the aerobic Chan-Lam coupling prepared via ball-milling strategy

被引：52

作者：

Khosravi, Armacian ^{[1
]}

Mokhtari, Javad ^{[1
]}

Naimi-Jamal, Mohammad Reza ^{[2
]}

Tahmasebi, Sharareh ^{[1
]}

Panahi, Leila ^{[2
]}

机构：

[1] Islamic Azad Univ, Dept Chem, Sci & Res Branch, POB 14515-775, Tehran, Iran

[2] Iran Univ Sci & Technol, Dept Chem, Res Lab Green Organ Synth & Polymers, POB 16846-13114, Tehran, Iran

来源：

RSC ADVANCES | 2017年 / 7卷 / 73期

关键词：

METAL-ORGANIC FRAMEWORKS; POROUS COORDINATION-POLYMER; ARYLBORONIC ACIDS; N-ARYLATION; MECHANOCHEMICAL PREPARATION; ARYL HALIDES; COPPER; ADSORPTION; IMIDAZOLES; PALLADIUM;

D O I：

10.1039/c7ra09772g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Nanoporous Cu-2(BDC)(2)(BPY)-MOF was used as efficient and reusable heterogeneous catalyst to effect the aerobic cross-coupling of aromatic amines and phenyl boronic acid (Chan-Lam coupling). Ball-milling strategy was utilized for the first as a powerful green and energy-efficient method for the synthesis of this nanoporous metal-organic framework. Certain ratio of metal ion and organic linkers were held to improve the quality of nanostructures. Cu-2(BDC)(2)(BPY) were characterized by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and Brunauer-Emmett-Teller (BET) surface area analysis.

引用

页码：46022 / 46027

页数：6

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