Volatile components of ozonized sunflower oil "OLEOZON®"

被引:10
作者
Ledea, O
Correa, T
Escobar, M
Rosado, A
Molerio, J
Hernández, C
Jardines, D
机构
[1] Natl Ctr Sci Res, Ozone Res Ctr, Havana, Cuba
[2] Natl Ctr Sci Res, Dept Analyt Chem, Havana 6880, Cuba
关键词
ozone; ozonation; OLEOZON (R); aldehydes; sunflower oil; GC/MS; purge and trap methods; volatiles;
D O I
10.1080/01919510108961994
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
During the ozonation of the triglycerides and unsaturated fatty acids from sunflower oil, aldehydes and carboxylic acids with three, six and nine carbon atoms are obtained, together with hydroperoxides, ozonides and other peroxide species. Some of them present relatively low boiling points, constituting the volatile fraction of ozonized sunflower oil (OLEOZON(R)). In the present work, the volatile fraction was characterized by Gas Chromatography - Mass Spectrometry (GC/MS) and Gas Chromatography (GC) combined with three different extraction techniques: gaseous purge with cold trap collection, gaseous purge with Tenax adsorption followed by a solvent elution and liquid-liquid extraction. The volatile fraction of OLEOZON(R) is composed by saturated and unsaturated aldehydes and carboxylic acids. Hexanal, nonanal, 3-nonenaldehyde and malonaldehyde were the main components of the volatile fraction.
引用
收藏
页码:121 / 126
页数:6
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