Thermodynamic properties of LiCl solutions in N-methylacetamide at 308.15-328.15 K

被引:1
作者
Manin, N. G. [1 ]
Kolker, A. M. [1 ]
机构
[1] Russian Acad Sci, Krestov Inst Solut Chem, Ivanovo 153045, Russia
关键词
thermochemistry; enthalpy of dissolution and dilution; N-methylacetamide; LiCl; relative partial enthalpy and heat capacity; ELECTROLYTE-SOLUTIONS; TETRAALKYLAMMONIUM SALTS; BUTYLAMMONIUM BROMIDE; AQUEOUS-SOLUTIONS; SODIUM-CHLORIDE; COEFFICIENTS; ENTHALPIES; SOLVATION; METHYLFORMAMIDE; DILUTION;
D O I
10.1134/S0036024417120184
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Enthalpies of dissolution of crystalline LiCl and enthalpies of dilution of LiCl solutions in N-methylacetamide (NMA) with electrolyte concentrations no greater than 0.32m are measured on an isoperibolic calorimeter at 308.15, 318.15, and 328.5 K. Standard enthalpies of the dissolution of LiCl in NMA are calculated at different temperatures. The thermodynamic properties of the solution and its components are calculated and analyzed in the investigated range of concentrations and temperatures.
引用
收藏
页码:2293 / 2301
页数:9
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