Inhibitive properties, adsorption and a theoretical study of 3,5-bis(n-pyridyl)-4-amino-1,2,4-triazoles as corrosion inhibitors for mild steel in perchloric acid

Corrosion inhibition of mild steel in molar perchloric acid by 3,5-bis(n-pyridyl)-4-amino-1,2,4-triazoles (n-PAT, n = 2,3 and 4) was studied at 30 degrees C using gravimetric and electrochemical impedance spectroscopy techniques. Protection efficiencies of 95% and 92% were obtained with 12 x 10(-4) M of 3-PAT and 4-PAT, respectively; while 2-PAT reached only 65%. The inhibiting properties of n-PAT were found to depend on the concentration and the order of increasing inhibition efficiency was correlated with the modification of the position of the nitrogen atom in the pyridinium substituent. It was shown that adsorption of 4-aminotriazole derivatives on the steel surface is consistent with the Langmuir adsorption isotherm and the obtained standard free energy of adsorption (Delta G(ads)(0)) values indicate that the corrosion inhibition of the mild steel in I M HClO4 is depends on both physic-and chemisorption. A significant correlation is obtained between inhibition efficiency and qnantum chemical parameters using semi-empirical qnantitative structure-activity relationships (QSAR) approach. (C) 2007 Elsevier Ltd. All rights reserved.