High-pressure homogenization of olivine-hosted CO2-rich melt inclusions in a piston cylinder: insight into the volatile content of primary mantle melts

Experimental homogenization of olivine-hosted melt inclusions representative of near-primary basic and ultrabasic magmas is a powerful approach to investigate the nature of their source regions and the melting conditions in Earth's mantle. There is growing evidence that the total CO2 contents of olivine-hosted melt inclusions may reach values of the order of a single to several weight percent, especially in intraplate continental basalts. To be able to homogenize melt inclusions with such high CO2 contents, we developed a technique allowing for heat treating of the melt inclusions under hydrostatic pressures up to 3-4 GPa in a piston cylinder, using thick-walled Au-80-Pd-20 containers and molten NaCl as the surrounding medium for the inclusion-bearing olivines. We applied this technique to olivine phenocrysts from Thueyts basanite, Bas-Vivarais volcanic province, French Massif Central. Thueyts melt inclusions were chosen because of their high CO2 contents, as indicated by up to 1.19 wt % dissolved CO2 in the glasses and by the presence of shrinkage bubbles containing abundant carbonate microcrystals in addition to a CO2 fluid phase. The homogenization experiments were conducted at pressures of 1.5 to 2.5 GPa, temperatures of 1275 and 1300 degrees C, and run durations of 30 min. In all the melt inclusions treated at 2.5 GPa-1300 degrees C and half of those treated at 2 GPa-1300 degrees C, we were able to completely homogenize the inclusions, as indicated by the disappearance of the starting bubbles, and we obtained total CO2 contents ranging from 3.2 wt % to 4.3 wt % (3.7 wt % on average). In all the other melt inclusions (equilibrated at 1.5 or 2 GPa and 1300 degrees C or at 2.5 GPa-1275 degrees C), we obtained lower and more variable total CO2 contents (1.4 wt % to 2.9 wt %). In the inclusions with the highest total CO2 contents, the size of the shrinkage bubble was in most cases small (< 5 vol %) to medium (< 10 vol %): this is a strong argument in favor of an origin of these melt inclusions by homogeneous entrapment of very CO2-rich basanitic liquids (similar to 4 wt %) at pressures of 2 to 2.5 GPa. The lower total CO2 contents measured in some inclusions could reflect a natural variability in the initial CO2 contents, due for instance to melt entrapment at different pressures, or CO2 loss by decrepitation. An alternative scenario is heterogeneous entrapment of basanitic liquid plus dense CO2 fluid at lower pressures but still at least on the order of 1 GPa as indicated by dissolved CO2 contents up to 1.19 wt % in the glasses of unheated melt inclusions. Whatever the scenario, the basanites from the Bas-Vivarais volcanic province were generated in a mantle environment extremely rich in carbon dioxide.