Effects of cadmium salts on the structure, morphology and optical properties of acidic chemical bath deposited CdS thin films

被引：30

作者：

Cao, M. ^{[1
,2
]}

Sun, Y. ^{[1
]}

Wu, J. ^{[1
]}

Chen, X. ^{[1
]}

Dai, N. ^{[1
]}

机构：

[1] Chinese Acad Sci, Natl Lab Infrared Phys, Shanghai Inst Tech Phys, Shanghai 200083, Peoples R China

[2] Shanghai Univ, Sch Mat Sci & Engn, Shanghai 200072, Peoples R China

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2010年 / 508卷 / 02期

关键词：

CdS thin films; Chemical bath deposition; Annealing; Photoluminescence; PHYSICAL-PROPERTIES; GROWTH;

D O I：

10.1016/j.jallcom.2010.08.066

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

CdS thin films were deposited from different cadmium salts by using acidic chemical bath deposition (CBD) process. Quality characterizations were performed using different methods such as scanning electron microscopy (SEM), X-ray diffraction (XRD) and photoluminescence (PL). The crystal quality of CdS thin films was improved after CdCl2 thermal annealing at 380 degrees C. A compact structure of CdS thin films can be obtained by using CdCl2 in comparison with the other cadmium salts. Although a Cd/S molar ratio of similar to 1 was used in our experiments, strong PL signals confirmed the high quality of CdS thin films. (c) 2010 Elsevier B.V. All rights reserved.

引用

页码：297 / 300

页数：4

共 23 条

[1]

Ashour H, 2001, PHYS STATUS SOLIDI A, V184, P175, DOI 10.1002/1521-396X(200103)184:1<175::AID-PSSA175>3.0.CO

[2]

2-M

[3] Novel approach to the deposition of CdS by chemical bath deposition: the deposition of crystalline thin films of CdS from acidic baths [J].

Boyle, DS ;

O'Brien, P ;

Otway, DJ ;

Robbe, O .

JOURNAL OF MATERIALS CHEMISTRY, 1999, 9 (03) :725-729

[4] Structural, optical and electrical characterization of In/CdS/glass thermally annealed system [J].

Castillo, SJ ;

Mendoza-Galván, A ;

Ramírez-Bon, R ;

Espinoza-Beltrán, FJ ;

Sotelo-Lerma, M ;

González-Hernández, J ;

Martínez, G .

THIN SOLID FILMS, 2000, 373 (1-2) :10-14

[5] Effects of deposition time and temperature on the optical properties of air-annealed chemical bath deposited CdS films [J].

Cetinorgu, E. ;

Gumus, C. ;

Esen, R. .

THIN SOLID FILMS, 2006, 515 (04) :1688-1693

[6] Growth behavior and microstructure of CdS thin films deposited by an electrostatic spray assisted vapor deposition (ESAVD) process [J].

Choy, KL ;

Su, B .

THIN SOLID FILMS, 2001, 388 (1-2) :9-14

[7] Grain size dependence of the bandgap in chemical bath deposited CdS thin films [J].

Cortes, A ;

Gomez, H ;

Marotti, RE ;

Riveros, G ;

Dalchiele, EA .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2004, 82 (1-2) :21-34

[8] Modelling of the structure of CdS thin films [J].

Gibson, PN ;

Özsan, ME ;

Lincot, D ;

Cowache, P ;

Summa, D .

THIN SOLID FILMS, 2000, 361 :34-40

[9]

Hernandez J.A., 2006, THIN SOLID FILMS, V511-512, P143

[10] Thermal annealing effect on structural and electrical properties of chemical bath-deposited CdS films [J].

Hiie, J. ;

Muska, K. ;

Valdna, V. ;

Mikli, V. ;

Taklaja, A. ;

Gavrilov, A. .

THIN SOLID FILMS, 2008, 516 (20) :7008-7012

← 1 2 3 →