Characterization of low-spin ferric hydroperoxo complexes with N,N′-dimethyl-N,N′-bis(2-pyridylmethyl)-1,2-diaminoethane

被引：18

作者：

Duban, EA ^{[1
]}

Bryliakov, KP ^{[1
]}

Talsi, EP ^{[1
]}

机构：

[1] Russian Acad Sci, Siberian Branch, GK Boreskov Inst Catalysis, Novosibirsk 630090, Russia

来源：

MENDELEEV COMMUNICATIONS | 2005年 / 15卷 / 01期

基金：

俄罗斯基础研究基金会;

关键词：

D O I：

10.1070/MC2005v015n01ABEH001981

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hydroperoxo intermediates formed by the interaction of [Fe-II(BPMEN)(MeCN)(2)](ClO4)(2) [BPMEN = NN'-dimethyI-NN'-bis(2-pyridylmethyl)-1,2-diaminoethaneI with H2O2 in a CH2Cl2-MeCN mixture were characterised using EPR spectroscopy.

引用

页码：12 / 14

页数：3

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