Influence of precursor chemistry and growth temperature on the electrical properties of SrTiO3-based metal-insulator-metal capacitors grown by atomic layer deposition
[2] Univ Helsinki, Dept Chem, FIN-00014 Helsinki, Finland
来源:
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B
|
2011年
/
29卷
/
01期
基金:
芬兰科学院;
关键词:
D O I:
10.1116/1.3525280
中图分类号:
TM [电工技术];
TN [电子技术、通信技术];
学科分类号:
0808 ;
0809 ;
摘要:
SrTiO3 thin films were grown to thicknesses in the range of 18-30 nm by atomic layer deposition using Sr((Pr3Cp)-Pr-i)(2) and (CpMe5)Ti(OMe)(3) as strontium and titanium precursors at 250 and 300 degrees C. Water or ozone was used as oxygen precursor. The films were amorphous in as-deposited state, but crystallized as cubic SrTiO3 after annealing at 650 degrees C. The highest permittivity values, 60-65, were achieved in the films deposited with ozone at 300 degrees C. The films grown at 250 degrees C tended to possess markedly lower leakage currents than those grown at 300 degrees C. (C) 2011 American Vacuum Society. [DOI: 10.1116/1.3525280]