Luminescent binuclear Zinc(II) organic framework as bifunctional water-stable chemosensor for efficient detection of antibiotics and Cr(VI) anions in water

To achieve the ultrastable LMOFs with predominant luminescent sensing performances, the aromatic pi-electron mixed ligands strategy was introduced, and the ternary LMOF of {[Zn-2(HDDB)(bib)(1.5)]center dot 3H(2)O}n (1), was fabricated based on 3,5-di(2',4'-dicarboxylphenyl)benozoic acid (H5DDB) and the N-donor of meta-bis(imidazol-1-yl)benzene (bib) under mixed solvothermal condition. LMOF 1 features the first reported 3D 3,4,4-c {6(2).8(3).10}{6(2).8}(2){6(3).8(2).10}(2) framework with 21.2 % porosity as well as high thermal and chemical stability. Further luminescent sensing showed that LMOF 1 as a bifunctional chemosensor possessing predominant detectability for sensitive detect the hexavalent chromates and nitroimidazoles/nitrofurans antibiotics in water through strong luminescent quenching effects, with excellent reusability as well as trace detection limits. Moreover, luminescent quenching mechanisms were further investigated from electron transfer and energy transfer viewpoints. (C) 2021 Elsevier B.V. All rights reserved.