A Green and Facile Synthesis of Carbon-Incorporated Co3O4 Nanoparticles and Their Photocatalytic Activity for Hydrogen Evolution

被引:24
作者
Gao, Libo [1 ,2 ]
Diwu, Jiangtao [3 ]
Zhang, Qiang [1 ,2 ]
Xu, Hongyan [3 ]
Chou, Xiujian [1 ,2 ]
Tang, Jun [1 ,2 ]
Xue, Chenyang [1 ,2 ]
机构
[1] North Univ China, Key Lab Instrumentat Sci & Dynam Measurement, Minist Educ, Taiyuan 030051, Shanxi, Peoples R China
[2] North Univ China, Sci & Technol Elect Test & Measurement Lab, Taiyuan 030051, Shanxi, Peoples R China
[3] North Univ China, Sch Mat Sci & Engn, Taiyuan 030051, Shanxi, Peoples R China
基金
中国国家自然科学基金;
关键词
CHEMICAL-VAPOR-DEPOSITION; WATER; OXIDATION; SPECTRA; OXIDES; FILMS;
D O I
10.1155/2015/618492
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Carbon-incorporated Co3O4 nanoparticles with an average diameter of 50 nm were prepared via a facile and environmentally friendly one-pot carbon-assisted method using degreasing cotton as a template as well as a reactant. The elemental analysis indicates the incorporation of carbon species into the Co3O4 nanoparticles and the XPS measurements demonstrate the presence of carbon species which comes from the incomplete combustion of the degreasing cotton. Interestingly, the resultant sample was able to split pure water into hydrogen under visible light irradiation without any cocatalyst, which is mainly due to the enhanced light absorption behavior confirmed by the UV-Vis absorption spectra. This facile method provided a potential strategy for applying narrow bandgap semiconductors in pure water splitting.
引用
收藏
页数:7
相关论文
共 22 条
  • [2] Hydrogen photo-evolution over the spinel CuCr2O4
    Boumaza, Souhila
    Bouarab, Rabah
    Trari, Mohamed
    Bouguelia, Aissa
    [J]. ENERGY CONVERSION AND MANAGEMENT, 2009, 50 (01) : 62 - 68
  • [3] Preparation, characterization and visible-light activity of carbon modified TiO2 with two kinds of carbonaceous species
    Chen, Chao
    Long, Mingce
    Zeng, Hui
    Cai, Weimin
    Zhou, Baoxue
    Zhang, Jingyi
    Wu, Yahui
    Ding, Dawei
    Wu, Deyong
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2009, 314 (1-2) : 35 - 41
  • [4] Semiconductor-based Photocatalytic Hydrogen Generation
    Chen, Xiaobo
    Shen, Shaohua
    Guo, Liejin
    Mao, Samuel S.
    [J]. CHEMICAL REVIEWS, 2010, 110 (11) : 6503 - 6570
  • [5] INTERPRETATION OF X-RAY PHOTOEMISSION SPECTRA OF COBALT OXIDES AND COBALT OXIDE SURFACES
    CHUANG, TJ
    BRUNDLE, CR
    RICE, DW
    [J]. SURFACE SCIENCE, 1976, 59 (02) : 413 - 429
  • [6] Simple preparation of ferromagnetic Co3O4 nanoparticles by thermal dissociation of the [CoII(NH3)6](NO3)2 complex at low temperature
    Farhadi S.
    Pourzare K.
    Sadeghinejad S.
    [J]. Journal of Nanostructure in Chemistry, 2013, 3 (1)
  • [7] Characterisation by X-ray photoelectron spectroscopy of thin MnxCo3-xO4 (1≥x≥0) spinel films prepared by low-temperature spray pyrolysis
    Gautier, JL
    Rios, E
    Gracia, M
    Marco, JF
    Gancedo, JR
    [J]. THIN SOLID FILMS, 1997, 311 (1-2) : 51 - 57
  • [8] THE RAMAN-SPECTRA OF CO3O4
    HADJIEV, VG
    ILIEV, MN
    VERGILOV, IV
    [J]. JOURNAL OF PHYSICS C-SOLID STATE PHYSICS, 1988, 21 (07): : L199 - L201
  • [9] Surface modification of TiO2 nanotubes by low temperature thermal treatment in C2H2 atmosphere
    Kado, Yuya
    Hahn, Robert
    Schmuki, Patrik
    [J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2011, 662 (01) : 25 - 29
  • [10] Highly efficient decomposition of pure water into H2 and O2 over NaTaO3 photocatalysts
    Kato, H
    Kudo, A
    [J]. CATALYSIS LETTERS, 1999, 58 (2-3) : 153 - 155