Subsystem dynamics in mixed quantum-classical systems

被引:25
|
作者
Toutounji, M [1 ]
Kapral, R [1 ]
机构
[1] Univ Toronto, Dept Chem, Chem Phys Theory Grp, Toronto, ON M5S 3H6, Canada
基金
加拿大自然科学与工程研究理事会;
关键词
D O I
10.1016/S0301-0104(01)00290-7
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Starting with the mixed quantum-classical Liouville equation, projection operator methods are used to derive an equation of motion for a quantum subsystem dissipatively interacting with a classical bath. The resulting generalized master equation is reduced to the Lindblad equation after making a Markovian approximation in the weak coupling limit. The bath subsystem dynamics is studied from a similar perspective. For situations where the classical subsystem consists of few degrees of freedom, or one is interested in the nature of the modifications of its dynamics as a result of coupling to a large, rapidly relaxing quantum bath, a classical analog of the Lindblad equation is derived and discussed. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:79 / 89
页数:11
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