Coordination chemistry of ene-1,1-diamines and a prototype "Carbodicarbene"

被引：359

作者：

Fuerstner, Alois ^{[1
]}

Alcarazo, Manuel ^{[1
]}

Goddard, Richard ^{[1
]}

Lehmann, Christian W. ^{[1
]}

机构：

[1] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 17期

关键词：

allenes; carbenes; enamines; gold; ylides;

D O I：

10.1002/anie.200705798

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Carbophilic Lewis acids can polarize a coordinated π-bond by a slippage mechanism. A series of stable ylid- or enolate gold complexes of ene-1,1-diamines not only emulate this property, but also reveal the exceptional donor capacity of such electron-rich olefin ligands. Moreover, the first metal complex of a tetraaminoallene is reported, which features a prototype carbodicarbene" ligand bound to a transition-metal template. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA."

引用

页码：3210 / 3214

页数：5

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