Magnesium-catalyzed hydroboration of organic carbonates, carbon dioxide and esters

被引：60

作者：

Cao, Xu ^{[1
]}

Wang, Weifan ^{[1
]}

Lu, Kai ^{[1
]}

Yao, Weiwei ^{[2
]}

Xue, Fei ^{[1
]}

Ma, Mengtao ^{[1
]}

机构：

[1] Nanjing Forestry Univ, Coll Sci, Nanjing 210037, Peoples R China

[2] Nanjing Univ Chinese Med, Coll Pharm, Nanjing 210023, Peoples R China

来源：

DALTON TRANSACTIONS | 2020年 / 49卷 / 09期

基金：

中国国家自然科学基金;

关键词：

SOLVENT-FREE HYDROBORATION; CYCLIC CARBONATES; TRANSFER HYDROGENATION; SELECTIVE REDUCTION; COMPLEXES SYNTHESES; METHANOL; CO2; DERIVATIVES; REACTIVITY; ALDEHYDES;

D O I：

10.1039/d0dt00465k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A low-valent magnesium(i) complex [((Xyl)Nacnac)Mg](2) was employed as a highly efficient precatalyst for the hydroboration of a variety of cyclic and linear organic carbonates, polycarbonates, CO2 and esters with HBpin under mild conditions. The resultant boronates can be used for the preparation of the corresponding value-added diols, triols or alcohols through hydrolysis.

引用

页码：2776 / 2780

页数：5

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