Boronic esters of a porphyrazine and its precursor

被引：8

作者：

Baseren, Sukran Cenikli ^{[1
]}

Ozcelik, Sennur ^{[1
]}

Gul, Ahmet ^{[1
]}

机构：

[1] Tech Univ Istanbul, Dept Chem, TR-34469 Istanbul, Turkey

来源：

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES | 2011年 / 15卷 / 7-8期

关键词：

porphyrazine; boronate complex; phenylboronic acid; maleonitrile; magnesium; ACID; COMPLEXES; DIOLS;

D O I：

10.1142/S1088424611003677

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Phenylboronic acid esters of an unsaturated precursor 1,2-dicyano-1,2-bis(2-hydroxyethylthio) ethylene and the magnesium porphyrazine derived from it have been prepared either by refluxing a mixture of the reagents in chloroform in the presence of molecular sieve or by solvent-free heating in an oven under reduced pressure. The two novel compounds have been characterized by elemental analysis together with ultraviolet-visible, infrared spectroscopy, proton nuclear magnetic resonance, carbon-13 nuclear magnetic resonance, boron-11 nuclear magnetic resonance, and mass spectra.

引用

页码：742 / 747

页数：6

共 31 条

[1] Synthesis and characterization of boronates derived from non-symmetric amino-bis-phenols [J].

Abreu, A ;

Alas, SJ ;

Beltrán, HI ;

Santillan, R ;

Farfán, N .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2006, 691 (03) :337-348

[2] SYNTHESIS AND CHARACTERIZATION OF CROWN-ETHER-CONTAINING PHTHALOCYANINES WITH GROUP-IV-A ELEMENTS [J].

AHSEN, V ;

YILMAZER, E ;

GUREK, A ;

GUL, A ;

BEKAROGLU, O .

HELVETICA CHIMICA ACTA, 1988, 71 (07) :1616-1621

[3] Octakis(ferrocene)-substituted porphyrazines [J].

Akku, H ;

Gül, A .

TRANSITION METAL CHEMISTRY, 2001, 26 (06) :689-694

[4] Boron-nitrogen macrocycles:: a new generation of calix[3]arenes [J].

Barba, V ;

Höpfl, H ;

Farfán, N ;

Santillan, R ;

Beltran, HI ;

Zamudio-Rivera, LS .

CHEMICAL COMMUNICATIONS, 2004, (24) :2834-2835

[5] Bisoxazaborolidines and boron complexes derived from tetradentate ligands:: synthesis and spectroscopic studies [J].

Barba, V ;

Rodríguez, A ;

Ochoa, ME ;

Santillan, R ;

Farfán, N .

INORGANICA CHIMICA ACTA, 2004, 357 (09) :2593-2601

[6] Direct synthesis of polymacrocyclic boron compounds. A convenient method for the synthesis of hemicarcerands [J].

Barba, Victor ;

Betanzos, Isabel .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2007, 692 (22) :4903-4908

[7] Phenyl boronic acid complexes of diols and hydroxyacids [J].

Bromba, Caleb ;

Carrie, Philippa ;

Chui, Jonathan K. W. ;

Fyles, Thomas M. .

SUPRAMOLECULAR CHEMISTRY, 2009, 21 (1-2) :81-88

[8] New perspectives for boronic esters in macrocyclic chemistry [J].

Farfán, N ;

Höpfl, H ;

Barba, V ;

Ochoa, ME ;

Santillan, R ;

Gómez, E ;

Gutiérrez, A .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 581 (1-2) :70-81

[9] Boron coordination compounds derived from organic molecules of biological interest [J].

Flores-Parra, A ;

Contreras, R .

COORDINATION CHEMISTRY REVIEWS, 2000, 196 :85-124

[10] Dynamic covalent self-assembled macrocycles prepared from 2-formyl-aryl-boronic acids and 1,2-amino alcohols [J].

Galbraith, Ewan ;

Kelly, Andrew M. ;

Fossey, John S. ;

Kociok-Koehn, Gabriele ;

Davidson, Matthew G. ;

Bull, Steven D. ;

James, Tony D. .

NEW JOURNAL OF CHEMISTRY, 2009, 33 (01) :181-185

← 1 2 3 4 →