Rigid, cross-conjugated macrocycles:: A cyclic alternative to 4,4′-bipyridines in supramolecular chemistry

被引:51
作者
Campbell, K [1 ]
McDonald, R [1 ]
Branda, NR [1 ]
Tykwinski, RR [1 ]
机构
[1] Univ Alberta, Dept Chem, Edmonton, AB T6G 2G2, Canada
关键词
D O I
10.1021/ol0156087
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
[GRAPHICS] The synthesis of two fully conjugated, rigid macrocyclic analogues to 4,4'-bipyridine is described. The use of these macrocycles in self assembly processes is demonstrated by axial coordination to metalloporphyrins, and one system (R = Me) has been characterized by single-crystal X-ray crystallography.
引用
收藏
页码:1045 / 1048
页数:4
相关论文
共 46 条
[1]   A NEW TYPE OF INFINITE 3D POLYMERIC NETWORK CONTAINING 4-CONNECTED, PERIPHERALLY LINKED METALLOPORPHYRIN BUILDING-BLOCKS [J].
ABRAHAMS, BF ;
HOSKINS, BF ;
ROBSON, R .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (09) :3606-3607
[2]   LIGAND-BINDING BY BUTADIYNE-LINKED PORPHYRIA DIMERS, TRIMERS AND TETRAMERS [J].
ANDERSON, HL ;
ANDERSON, S ;
SANDERS, JKM .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1995, (18) :2231-2245
[3]   Building molecular wires from the colours of life: conjugated porphyrin oligomers [J].
Anderson, HL .
CHEMICAL COMMUNICATIONS, 1999, (23) :2323-2330
[4]   MACROCYCLIC TETRAETHYNYLETHENE MOLECULAR SCAFFOLDING - PERETHYNYLATED AROMATIC DODECADEHYDRO[18]ANNULENES, ANTIAROMATIC OCTADEHYDRO[12]ANNULENES, AND EXPANDED RADIALENES [J].
ANTHONY, J ;
BOLDI, AM ;
BOUDON, C ;
GISSELBRECHT, JP ;
GROSS, M ;
SEILER, P ;
KNOBLER, CB ;
DIEDERICH, F .
HELVETICA CHIMICA ACTA, 1995, 78 (04) :797-817
[5]   The metal-directed self-assembly of three-dimensional porphyrin arrays [J].
Chichak, K ;
Branda, NR .
CHEMICAL COMMUNICATIONS, 2000, (13) :1211-1212
[6]   Phosphine-substituted porphyrins as supramolecular building blocks [J].
Darling, SL ;
Stulz, E ;
Feeder, N ;
Bampos, N ;
Sanders, JKM .
NEW JOURNAL OF CHEMISTRY, 2000, 24 (05) :261-264
[7]  
Drain CM, 1998, ANGEW CHEM INT EDIT, V37, P2344, DOI 10.1002/(SICI)1521-3773(19980918)37:17<2344::AID-ANIE2344>3.0.CO
[8]  
2-B
[9]  
Eisler S, 1999, ANGEW CHEM INT EDIT, V38, P1940, DOI 10.1002/(SICI)1521-3773(19990712)38:13/14<1940::AID-ANIE1940>3.0.CO
[10]  
2-8