A Thiacalix Basket and Its Anion-Dependent 2-D and 3-D Silver(I) Coordination Polymers via Exo-Coordination

被引：5

作者：

Ju, Huiyeong ^{[1
,2
]}

Park, In-Hyeok ^{[1
]}

Lee, Eunji ^{[1
,2
]}

Kim, Chungsik ^{[1
]}

Kim, Seulgi ^{[1
]}

Kuwahara, Shunsuke ^{[2
]}

Habata, Yoichi ^{[2
]}

Lee, Shim Sung ^{[1
]}

机构：

[1] Gyeongsang Natl Univ, Inst Nat Sci, Dept Chem & Res, Jinju 52828, South Korea

[2] Toho Univ, Dept Chem, 2-2-1 Miyama, Funabashi, Chiba 2748510, Japan

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2020年 / 2020卷 / 04期

关键词：

Calixarenes; Molecular baskets; Silver; Coordination polymers; exo-Coordination; TOPOLOGICAL ANALYSIS; STRUCTURAL-ANALYSIS; ALKALI-METAL; NETWORKS; MACROCYCLES; COMPLEXES; DERIVATIVES; DESIGN;

D O I：

10.1002/ejic.201901216

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Thiacalix[4]arene-bis-1,2;3,4-crown-2 (basket or L) was isolated. Herein we report the first examples of the calix basket complexes. The combination of the basket and silver(I) salts afforded anion-dependent coordination polymers with different dimensionalities. The AgClO4 complex 1, {[Ag-2(L)(CH3OH)(ClO4)(2)]center dot 4CHCl(3)}(n) has a 2-D square-grid network, in which silver(I) atoms link the baskets to form a 1-D ribbon and these are crosslinked by perchlorate ions. While, the AgPF6 complex 2, {[Ag(L)(CH3OH)](PF6)}(n) exhibits a multichannel type 3-D framework with nbo-a topology. Since the basket acts as an ideal exo-coordinating S-4-platform, the topologies of both products are highly sensitive to the anion coordination.

引用

页码：356 / 360

页数：5

共 46 条

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