Enhancing the Temperature Stability of 0.42PNN-0.21PZ-0.37PT Ceramics through Texture Engineering

Although the MPB composition 0.42PNN-0.21PZ-0.37PT ceramic has high piezoelectric properties, its temperature stability at room temperature is rather poor due to the low phase-transition temperature. By texture engineering using BaTiO3 (BT) as the template, the temperature stability of this material can be greatly improved. In the temperature range from room temperature up to 140 degrees C, the high effective piezoelectric strain constant d(33)* of 0.42PNN-0.21PZ-0.37PT-3BT only changed by 4.9% from 1278 to 1215 pm/V, while the d(33)* of the nontextured counterpart changed by 46.7% from the room temperature value of 920 pm/V with the maximum deviation to 1350 pm/V at 80 degrees C. In addition, the textured ceramic has higher piezoelectric properties, lower dielectric loss, and slightly higher coercive field. The room-temperature figure-of-merit d(33) x g(33) for PNN-PZT-2BT is increased by as much as 42% compared with the nontextured counterpart. Our results demonstrated that texture engineering is an effective way to improve the temperature stability of the MPB composition piezoceramics.