Magnetodielectric effect in a metamaterial consisting of xerogel with embedded ε-Fe2O3 iron oxide nanoparticles

被引:5
作者
Dubrovskiy, A. A. [1 ]
Balaev, D. A. [1 ]
Krasikov, A. A. [1 ]
Yakushhkin, S. S. [2 ]
Kirillov, V. L. [2 ]
Martyanov, O. N. [2 ]
机构
[1] Russian Acad Sci, Siberian Branch, Kiresnky Inst Phys, Krasnoyarsk Sci Ctr, Krasnoyarsk 660036, Russia
[2] Russian Acad Sci, Siberian Branch, Boreskov Inst Catalysis, Novosibirsk 630090, Russia
基金
俄罗斯科学基金会;
关键词
MAGNETIC-PROPERTIES; HIGH-TEMPERATURE; PHASE; RAMAN;
D O I
10.1016/j.ssc.2018.11.020
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
The epsilon-Fe2O3 iron oxide is a fairly rare polymorphic modification, which only exists in the form of nanoparticles embedded, as a rule, into a silica gel matrix. This magnetically ordered iron oxide, which exhibits a significant room-temperature coercivity, is a ferroelectric; therefore, the magnetoelectric and magnetodielectric properties of this material evoke keen interest. In this work, we investigate the magnetodielectric (MD) effect in a metamaterial consisting of xerogel SiO2 with embedded epsilon-Fe2O3 nanoparticles 9 nm in size on average in a concentration of 20 mass.%. This bulk material exhibits the MD effect in a wide temperature range. The temperature behavior of the permittivity is related to the magnetic state of the epsilon-Fe2O3 oxide, which undergoes the magnetic transition from the magnetically hard to magnetically soft phase in the temperature range of 80-150 K, indicating the interplay of the epsilon-Fe2O3 magnetic and charge subsystems.
引用
收藏
页码:27 / 29
页数:3
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