共 28 条
Morphology and natural wettability properties of sol-gel derived TiO2-SiO2 composite thin films
被引:103
作者:
Houmard, M.
[1
,2
]
Riassetto, D.
[2
]
Roussel, F.
[3
]
Bourgeois, A.
Berthome, G.
[1
]
Joud, J. C.
[1
]
Langlet, M.
[2
]
机构:
[1] Inst Natl Polytech Grenoble, LTPCM, F-38402 St Martin Dheres, France
[2] Inst Natl Polytech Grenoble, LMGP, F-38402 St Martin Dheres, France
[3] Inst Natl Polytech Grenoble, CMTC, St Martin Dheres, France
关键词:
super-hydrophilicity;
TiO2-SiO2 thin films;
sol-gel;
self-cleaning surfaces;
D O I:
10.1016/j.apsusc.2007.06.072
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
Previous studies suggest that granular interfaces induce a natural and persistent super-hydrophilicity in TiO2-SiO2 composite thin films deposited by sol-gel route. This effect enables to consider self-cleaning applications that do not require a permanent UV exposure, whereas such a permanent exposure is necessary for pure TiO2 films. In this study, TiO2-SiO2 composite thin films have been deposited from a TiO2 anatase crystalline suspension and different SiO2 Polymeric sols. Wettability studies show that a suitable control of the TiO2-SiO2 mixed sol formulations noticeably enhances persistence of the natural super-hydrophilicity in composite films. It is shown that, beside granular interface effects, modifications in the composite film morphologies can noticeably influence wettability properties. (c) 2007 Elsevier B.V. All rights reserved.
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页码:1405 / 1414
页数:10
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