Hybrid Material Constructed from Hg(NCS)2 and 2,4,6-Tris(2-pyrimidyl)-1,3,5-triazine (TPymT): Coordination of TPymT in a 2,2′-Bipyridine-Like Mode

被引：33

作者：

Safin, Damir A. ^{[1
]}

Holmberg, Rebecca J. ^{[1
]}

Burgess, Kevin M. N. ^{[1
]}

Robeyns, Koen ^{[2
]}

Bryce, David L. ^{[1
]}

Murugesu, Muralee ^{[1
]}

机构：

[1] Univ Ottawa, Dept Chem, Ottawa, ON K1N 6N5, Canada

[2] Catholic Univ Louvain, MOST Inorgan Chem, Inst Condensed Matter & Nanosci, B-1348 Louvain, Belgium

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2015年 / 03期

基金：

加拿大自然科学与工程研究理事会; 加拿大创新基金会;

关键词：

Organic-inorganic hybrid materials; Mercury; N ligands; Coordination modes; Structure elucidation; MERCURY(II) THIOCYANATE COMPLEXES; EXTENDED TERPYRIDYL; FRAMEWORK MATERIALS; CRYSTAL-STRUCTURE; METAL-COMPLEXES; ALFRED WERNER; SOLID-STATE; CHEMISTRY; POLYMERS; 2,4,6-TRIS(2-PYRIDYL)-1,3,5-TRIAZINES;

D O I：

10.1002/ejic.201402832

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A unique Hg-II coordination polymer has been synthesized through the reaction of 2,4,6-tris(2-pyrimidyl)-1,3,5-triazine (TPymT) with a stoichiometric mixture of HgCl2 and NH4NCS, thus leading to the formation of a 1D polymeric heteroleptic hybrid material [{Hg(NCS)(2)}(2)TPymT](n) (1). Two coordination pockets of TPymT in 1 are each coordinated to two Hg-II cations in an unprecedented 2,2'-bipyridine-like mode.

引用

页码：441 / 446

页数：6

共 54 条

[1] SYNTHESIS, STRUCTURE, AND SPECTROSCOPIC PROPERTIES OF COPPER(II) COMPOUNDS CONTAINING NITROGEN SULFUR DONOR LIGANDS - THE CRYSTAL AND MOLECULAR-STRUCTURE OF AQUA[1,7-BIS(N-METHYLBENZIMIDAZOL-2'-YL)-2,6-DITHIAHEPTANE]COPPER(II) PERCHLORATE [J].