NaxC60 thin films with Na concentration 0 <= x <= 3 were investigated using angle-dependent photoelectron spectroscopy. For low doping we observed two distinct fulleride phases coexisting with regions of pristine C-60. One of these fulleride phase is predominantly formed close to the surface and disappears after annealing and further addition of Na. At higher doping a phase with stoichiometry of x = 3 is formed. (C) 2007 Elsevier B.V. All rights reserved.