Corrosion resistance of Nd-Fe-B sintered magnets with intergranular addition of Cu60Zn40 powders

被引：17
作者：
Wu, Yeren [1 ]
Ni, Junjie [1 ]
Ma, Tianyu [1 ]
Yan, Mi [1 ]
机构：
[1] Zhejiang Univ, Dept Mat Sci & Engn, State Key Lab Silicon Mat, Hangzhou 310027, Peoples R China
来源：
PHYSICA B-CONDENSED MATTER | 2010年 / 405卷 / 16期
关键词：
Nd-Fe-B sintered magnets; Cu60Zn40; powders; Corrosion resistance; NANOCRYSTALLINE NDFEB MAGNETS; BEHAVIOR; GA; CO; CU; NANOPOWDERS; NB; AL;
D O I：
10.1016/j.physb.2010.04.065
中图分类号：
O469 [凝聚态物理学];
学科分类号：
070205 ;
摘要：
Cu60Zn40 powders, as grain boundary modifiers, were added into Nd28.2Dy2.0FebalAl0.1Nb0.2Ga0.11B0.96 sintered magnets to improve the corrosion resistance of magnets. The corrosion resistance of magnets was investigated by polarization curve measurements in 3.5 wt% NaCl and 3.0 wt% NaOH solutions. It was found that the Cu60Zn40-added magnets had more positive corrosion potential E-corr and much lower corrosion current density i(corr) than the Cu60Zn40-free one in both solutions, indicating the improvement of the corrosion resistance by Cu60Zn40 intergranular addition. Promotion of the electrochemical potential of the intergranular phase, formation of the Nd (Fe, Cu)(2) phase, the uniform distribution of the Nd-rich phase and increase of the magnet density were found to be responsible for the improvement of the corrosion resistance. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码：3303 / 3307
页数：5
相关论文
共 19 条
  • [1] EFFECT OF MICROSTRUCTURE ON THE CORROSION BEHAVIOR OF NDFEB AND NDFECOALB MAGNETS
    CAMP, FE
    KIM, AS
    [J]. JOURNAL OF APPLIED PHYSICS, 1991, 70 (10) : 6348 - 6350
  • [2] Effect of SiO2 nanopowders on magnetic properties and corrosion resistance of sintered Nd-Fe-B magnets
    Cui, X. G.
    Yan, M.
    Ma, T. Y.
    Luo, W.
    Tu, S. J.
    [J]. JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2009, 321 (05) : 392 - 395
  • [3] Effects of Cu nanopowders addition on magnetic properties and corrosion resistance of sintered Nd-Fe-B magnets
    Cui, X. G.
    Yan, M.
    Ma, T. Y.
    Yu, L. Q.
    [J]. PHYSICA B-CONDENSED MATTER, 2008, 403 (23-24) : 4182 - 4185
  • [4] Electrochemical characterization of galvanically coupled single phases and nanocrystalline NdFeB-based magnets in NaCl solutions
    El-Moneim, AA
    Gebert, A
    [J]. JOURNAL OF APPLIED ELECTROCHEMISTRY, 2003, 33 (09) : 795 - 805
  • [5] The influence of Co and Ga additions on the corrosion behavior of nanocrystalline NdFeB magnets
    El-Moneim, AA
    Gebert, A
    Uhlemann, M
    Gutfleisch, O
    Schultz, L
    [J]. CORROSION SCIENCE, 2002, 44 (08) : 1857 - 1874
  • [6] A study on the corrosion behavior of the (Nd, MM)2(Fe, Co, Ni)14B-type sintered magnets
    Hosseini, H. R. Madaah
    Dadoo, A.
    Dolati, A.
    Kianvash, A.
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2006, 419 (1-2) : 337 - 341
  • [7] Investigation of simultaneous enhancement of remanence and coercivity in Nd-Fe-B/Nb mixed-powder sintered magnets
    Hu, JF
    Liu, YL
    Yin, ML
    Wang, YZ
    Hu, BP
    Wang, ZX
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 1999, 288 (1-2) : 226 - 228
  • [8] Long-term corrosion tests on Nd-Fe-B sintered magnets
    Kaszuwara, W
    Leonowicz, M
    [J]. MATERIALS LETTERS, 1999, 40 (01) : 18 - 22
  • [9] Corrosion mechanism of RE-Fe-Co-Cu-Ga-Al-B magnets
    Katter, M
    Zapf, L
    Blank, R
    Fernengel, W
    Rodewald, W
    [J]. IEEE TRANSACTIONS ON MAGNETICS, 2001, 37 (04) : 2474 - 2476
  • [10] High performance NdFeB magnets
    Kim, AS
    Camp, FE
    [J]. JOURNAL OF APPLIED PHYSICS, 1996, 79 (08) : 5035 - 5039
12