Assembly of a porous three-dimensional coordination polymer:: Crystal structure of {[La2(adipate)3(H2O)4]6H2O}n

被引：191
作者：
Kiritsis, V [1 ]
Michaelides, A
Skoulika, S
Golhen, S
Ouahab, L
机构：
[1] Univ Ioannina, Dept Chem, GR-45110 Ioannina, Greece
[2] Univ Rennes 1, Chim Solide & Inorgan Mol Lab, UMR 6511, F-35042 Rennes, France
来源：
INORGANIC CHEMISTRY | 1998年 / 37卷 / 13期
关键词：
D O I：
10.1021/ic980014u
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The structure and dehydration behavior of the porous 3D coordination polymer {[La-2(adipate)(3)(H2O)(4)]6H(2)O}(n) are described. Each La3+ is coordinated by nine oxygen atoms belonging to five carboxylate ligands and to two water molecules. Large infinite interconnected channels filled with hydrogen-bonded water molecules are formed in the structure. Upon heating, this compound transforms reversibly into a nonporous lower hydrate.
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页码：3407 / +
页数：5
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