Origins and implications of magnesium isotopic heterogeneity in Fe-Ti oxides in layered mafic intrusions

To constrain the mechanisms governing the extremely large variations of Mg and Fe isotopes in magmatic Fe-Ti oxides in layered mafic intrusions, we investigate Mg isotopic compositions of magnetite, coupled with its chemical data and whole-rock major element and Sr-Nd isotope compositions from the Baima layered mafic intrusion in the Emeishan large igneous province, SW China. The Baima intrusion is mainly composed of magnetite-wehrlite and magnetite-troctolite (i.e., oxide-rich rocks) in the Lower Zone, and troctolite and gabbro (i.e., oxide-barren rocks) in the Middle and Upper Zones. Magnetite separates display large Mg isotopic variation, with delta Mg-26 ranging from -0.17 +/- 0.06 to +0.58 +/- 0.04 parts per thousand in the oxide-rich rocks and from -0.18 +/- 0.06 to +0.98 +/- 0.04 parts per thousand in the oxide-barren ones. The lack of correlation of delta Mg-26 with trace elements in magnetite and whole-rock Sr-Nd isotopic compositions indicates that the large Mg isotopic variation in magnetite was not produced by fractional crystallization, magma mixing, crustal contamination, and/or trapped liquid shift. Instead, equilibrium isotope fractionation induced by Mg-Fe re-equilibration between magnetite and ilmenite at different subsolidus temperatures controlled the Mg isotopic variation in the oxide-rich rocks; and kinetic isotope fractionation driven by Mg-Fe inter-diffusion between magnetite and olivine and/or clinopyroxene dominated the oxide-barren rocks. Both processes were primarily controlled by the assemblage and modal abundance of coexisting minerals to which magnetite adjoins. Overall, fractional crystallization and subsequent subsolidus diffusion played crucial roles in the genesis of the Fe-Ti oxides in the Baima intrusion. Our results also reveal widespread isotope disequilibrium between coexisting minerals in mafic magma chambers and suggest that Mg isotope geochemistry has a great potential to characterize the formation of Fe-Ti oxides in layered mafic intrusions. (C) 2021 Elsevier Ltd. All rights reserved.