Seasonal variation of hydrophobic organic contaminant concentrations in the water-column of the Seine Estuary and their transfer to a planktonic species Eurytemora affinis (Calanoid, copepod).: Part 2:: Alkylphenol-polyethoxylates

被引：75

作者：

Cailleaud, K. ^{[1
,2
,3
]}

Forget-Leray, J. ^{[3
]}

Souissi, S. ^{[2
]}

Lardy, S. ^{[1
]}

Augagneur, S. ^{[1
]}

Budzinski, H. ^{[1
]}

机构：

[1] Univ Bordeaux 1, Lab Phys Toxico Chim Environment, CNRS, UMR 5255,ISM, F-33405 Talence, France

[2] Univ Sci & Technol Lille, CNRS, UMR Ecosyst Littoraux & Cotiers 8013, F-62930 Wimereux, France

[3] GDR IMOPHYS, UPRES EA3222, Lab Ecotoxicol Milieux Aquat, Fac Sci & Techn Havre, F-76058 Le Havre, France

来源：

CHEMOSPHERE | 2007年 / 70卷 / 02期

关键词：

nonylphenol; crustacean; bioaccumulation; Estuary; water-column; alkylphenol-polyethoxylates;

D O I：

10.1016/j.chemosphere.2007.06.012

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

The occurrence and fate of alkylphenols in various matrices of the Seine River Estuary were studied. Nonylylphenols (NP) and nonylphenol polethoxylates (NPEs) were monitored in surface dissolved water, suspended particulate matter (SPM) and in a copepod, Eurytemora affinis from November 2002 to January 2004. NPs, nonylphenol mono and diethoxylates (NP1EO, NP2EO) and nonylphenol-ethoxy-acetic-acid (NP1EC) were detected and measured in all dissolved water and SPM samples whereas nonylphenoxy-acetic-acid (NP2EC) was only found sporadically in dissolved water samples. Seasonal variation of total concentrations of NPs and NPEs, ranging, respectively from 399 to 2214 ng l(-1) and from 405 to 9636 ng g(-1), were measured in the dissolved water and in the SPM. Significant decreases were observed in the water-column during the maximum biological activity periods in spring and autumn. Furthermore, increasing levels were observed in the SPM during the winter period. High concentrations of NP1EO and NP were detected in all copepod samples, ranging from 3423 to 6406 ng g(-1). This study is the first to report high levels of endocrine disruptors in estuarine copepods. (C) 2007 Elsevier Ltd. All rights reserved.

引用

页码：281 / 287

页数：7

共 39 条

[1] BEHAVIOR OF ALKYLPHENOL POLYETHOXYLATE SURFACTANTS IN THE AQUATIC ENVIRONMENT .1. OCCURRENCE AND TRANSFORMATION IN SEWAGE-TREATMENT [J].

AHEL, M ;

GIGER, W ;

KOCH, M .

WATER RESEARCH, 1994, 28 (05) :1131-1142

[2] Concentrations of alkyphenol polyethoxylates entering UK estuaries [J].

Blackburn, MA ;

Kirby, SJ ;

Waldock, MJ .

MARINE POLLUTION BULLETIN, 1999, 38 (02) :109-118

[3] Long-term exposure to 4-nonylphenol affects sexual differentiation and growth of the amphipod Corophium volutator (Pallas, 1766) [J].

Brown, RJ ;

Conradi, M ;

Depledge, MH .

SCIENCE OF THE TOTAL ENVIRONMENT, 1999, 233 (1-3) :77-88

[4] Seasonal variations of hydrophobic organic contaminant concentrations in the water-column of the Seine Estuary and their transfer to a planktonic species Eurytemora affinis (Calanoida, copepoda).: Part 1:: PCBs and PAHs [J].

Cailleaud, K. ;

Forget-Leray, J. ;

Souissi, S. ;

Hilde, D. ;

LeMenach, K. ;

Budzinski, H. .

CHEMOSPHERE, 2007, 70 (02) :270-280

[5] DETERMINATION OF NONYLPHENOLS AS PENTAFLUOROBENZYL DERIVATIVES BY CAPILLARY GAS-CHROMATOGRAPHY WITH ELECTRON-CAPTURE AND MASS-SPECTROMETRIC DETECTION IN ENVIRONMENTAL MATRICES [J].

CHALAUX, N ;

BAYONA, JM ;

ALBAIGES, J .

JOURNAL OF CHROMATOGRAPHY A, 1994, 686 (02) :275-281

[6] TRACE-METAL DISTRIBUTION, PARTITION AND FLUXES IN THE SEINE ESTUARY (FRANCE) IN LOW DISCHARGE REGIME [J].

CHIFFOLEAU, JF ;

COSSA, D ;

AUGER, D ;

TRUQUET, I .

MARINE CHEMISTRY, 1994, 47 (02) :145-158

[7] BIOACCUMULATION OF 4-NONYLPHENOL IN MARINE ANIMALS - A REEVALUATION [J].

EKELUND, R ;

BERGMAN, A ;

GRANMO, A ;

BERGGREN, M .

ENVIRONMENTAL POLLUTION, 1990, 64 (02) :107-120

[8]

*EUR UN, 1999, RISK ASS 4 NON BRANC

[9]

European Union, 2005, COMM IMPL STRAT WAT

[10] Including transformation products into the risk assessment for chemicals:: The case of nonylphenol ethoxylate usage in Switzerland [J].

Fenner, K ;

Kooijman, C ;

Scheringer, M ;

Hungerbühler, K .

ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2002, 36 (06) :1147-1154

← 1 2 3 4 →