Dichloridobis(2-methyl-1,3-benzothiazole-κN)zinc(II)

被引：2
|
作者：
Roh, Soo-Gyun [1 ]
Jeong, Jong Hwa [1 ]
机构：
[1] Kyungpook Natl Univ, Dept Chem, Taegu 702701, South Korea
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2007年 / 63卷
关键词：
D O I：
10.1107/S1600536807039104
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The reaction of 4-[(2-mercaptophenyl)amino]pent-3-en-2-one with ZnCl2 in CH2Cl2 gives the title complex, [ZnCl2(C8H7NS)(2)], as a brown crystalline product in which 4-[(2-mercaptophenyl)amino]pent-3-en-2-one has been converted into 2-methylbenzothiazole. The Zn atom is coordinated by two chloride ions and binds to the N atoms of two 2-methylbenzothiazole ligands in a distorted tetrahedral arrangement.
引用
收藏
页码：M2334 / U801
页数：8
相关论文
共 50 条
  • [1] ALPHA-HYDROXYBENZYLATION AND BENZYLIDENATION OF METHYL-GROUP IN 2-METHYL-1,3-BENZOXAZOLE AND 2-METHYL-1,3-BENZOTHIAZOLE
    DRYANSKA, V
    IVANOV, C
    SYNTHESIS-STUTTGART, 1976, (01): : 37 - 38
  • [2] Bis(2-amino-1,3-benzothiazole-κN3)dichloridozinc(II) ethanol hemisolvate
    Kim, Young-Inn
    Kang, Sung Kwon
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2012, 68 : M178 - U904
  • [3] trans-bis(2-amino-1,3-benzothiazole-κN3)dichlorocopper(II)
    Maniukiewicz, W
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2004, 60 : M340 - M341
  • [4] Bis(7-amino-1,3-benzothiazole-κN3)dichlorozinc(II)
    Popovic, Z
    Pavlovic, G
    Soldin, Z
    Tralic-Kulenovic, V
    Racané, L
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2003, 59 : M4 - M6
  • [5] Bis(2-amino-6-methyl-1,3-benzothiazole-κN3)bis(4-nitrobenzoato-κO1)zinc
    Sun, Xue-Tong
    Wang, Xiu-Guang
    Zhao, Xiao-Jun
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M933 - U1061
  • [6] Dichloridobis(2-phenylpyridine-kappa N)-zinc(II)
    Dharmalingam, Sivanesan
    Lee, Ha-Jin
    Yoon, Sungho
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M431 - +
  • [7] Dichloridobis(phenanthridine-κN)zinc(II)
    Khoshtarkib, Zeinab
    Ebadi, Amin
    Alizadeh, Robabeh
    Ahmadi, Roya
    Amani, Vahid
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M739 - U521
  • [8] Dichloridobis(isoquinoline-κN)zinc(II)
    Li, Meng-Jiao
    Nie, Jing-Jing
    Xu, Duan-Jun
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : M876 - U197
  • [9] Tetra-μ-acetato-κ8 O:O′-bis[(2-amino-1,3-benzothiazole-κN)copper(II)] butanol disolvate
    Sun, Yi-Feng
    Lu, Jing-Rong
    Zheng, Ze-Bao
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : M1881 - U875
  • [10] ZINC(II), CADMIUM(II) AND MERCURY(II) COMPLEXES OF 2-METHYL-BENZOTHIAZOLE
    PEYRONEL, G
    GIUSTI, A
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1981, 37 (02) : 71 - 75
12345