Speciation of zinc and copper in stormwater pavement runoff from airside and landside aviation land uses

被引:22
作者
Gnecco, I. [1 ]
Sansalone, J. J. [2 ]
Lanza, L. G. [1 ]
机构
[1] Univ Genoa, Dept Civil Environm & Architectural Engn, I-16145 Genoa, Italy
[2] Univ Florida, Gainesville, FL USA
关键词
rainfall-runoff; first-flush; metals; land use; aviation; pavement; Particulate matter; speciation; BMPs;
D O I
10.1007/s11270-008-9659-2
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The transport, bioavailability and fate of aqueous metals in rainfall-runoff are determined, in part, by speciation. In the framework of a monitoring program to investigate the predominant species of zinc, copper, and water chemistry in runoff subject to aviation land use and activities, two rainfall-runoff monitoring stations were installed at the international airport of Genoa (Italy). One catchment was a boarding area (airside) apron and the other a parking area for vehicles (landside). Utilizing water chemistry analyses, ion balances and speciation modelling for a series of five event loadings for each site, results indicated that Zn2+ dominated Zn speciation and Cu complexes with carbonate or dissolved organic matter, dominated Cu speciation. With respect to wash-off processes a mass limited behaviour was generally observed for particulate matter (measured as TSS) and TOC; while the mass delivery of aqueous metal species tended to be more proportionate with respect to runoff volume.
引用
收藏
页码:321 / 336
页数:16
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