Synthesis and crystal structure of CsCu3O2, containing a new type of oxocuprate(I) polyanion

被引：4

作者：

Sofin, M ^{[1
]}

Peters, EM ^{[1
]}

Jansen, M ^{[1
]}

机构：

[1] Max Planck Inst Festkorperforsch, D-70569 Stuttgart, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2003年 / 629卷 / 14期

关键词：

caesium copper oxide; crystal structure; azide/nitrate route;

D O I：

10.1002/zaac.200300309

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

CsCu3O2 was prepared via the azide route. Stoichiometric mixtures of the precursors (CsN3, Cu2O and CuO) were heated in a special regime up to 450 degreesC and annealed at this temperature for 50 h in silver crucibles. Single crystals have been grown by subsequent annealing of as prepared powders at 450 degreesC for 2000 h in silver crucibles, which were sealed in glass ampoules under dried Ar. According to the X-ray analysis of the crystal structure (P3ml, Z = 1, a = 5.250(1), c = 5.442(1) Angstrom, gamma = 120degrees) copper is linearly coordinated by oxygen atoms. The CuO2-dumb-bells are connected to an infinite two-dimensional (infinityCu3O2)-Cu-2-network. CsCu3O2 is isostructural with CsCu3S2, CsAu3S2, CsAu3Se2 and RbAu3Se2.

引用

页码：2435 / 2437

页数：3

共 50 条

[11] Synthesis, Crystal Structure and Physicochemical Proprieties of a Cytosine Selenomolybdate Based on Strandberg-Type [Se2Mo5O21]4- Polyanion [J].

Nagazi, Ichraf ;

Haddad, Amor .

JOURNAL OF CLUSTER SCIENCE, 2014, 25 (02) :627-638

[12] Synthesis and crystal structure of a new silver(I) complex [J].

Adhami, F ;

Ghassemzadeh, M ;

Heravi, MM ;

Taeb, A ;

Neumüller, B .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1999, 625 (09) :1411-1412

[13] Synthesis, Crystal Structure of a New Structure Type, and Thermal Analysis of the Ammonium Borophosphate (NH4)2[B2P3O11(OH)] [J].

Foerg, Katharina ;

Hoeppe, Henning A. .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2017, 643 (12) :766-771

[14] The crystal structures of CsAu3S2, RbAu3Se2 and CsAu3Se2 and their relationship to the CsCu3S2 structure type [J].

Klepp, KO ;

Weithaler, C .

JOURNAL OF ALLOYS AND COMPOUNDS, 1996, 243 (1-2) :1-5

[15] Synthesis and crystal structure of a new A type pyridine iodide [J].

Zhang, Y ;

Wu, JY ;

Yu, WT ;

Tian, YP ;

Jiang, MH .

CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2002, 18 (10) :1020-1022

[16] Synthesis and crystal structure of Fe2BP3O12 [J].

Chen, HH ;

Ge, MH ;

Yang, XX ;

Mi, JX ;

Zhao, JT .

JOURNAL OF INORGANIC MATERIALS, 2004, 19 (02) :429-432

[17] Synthesis and crystal structure of a new samarium borosilicate compound Sm3BSi2O10 [J].

Chi, LS ;

Chen, HY ;

Deng, SQ ;

Zhuang, HH ;

Huang, JS .

JOURNAL OF ALLOYS AND COMPOUNDS, 1996, 242 (1-2) :1-5

[18] Synthesis, crystal structure and properties of a quaternary oxide with a new structure type, BiGaTi4O11 [J].

Yamane, Hisanori ;

Yagi, Ryota ;

Hosono, Akira ;

Masubuchi, Yuji .

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2019, 75 :702-+

[19] Synthesis and Crystal Structure of a New Hydrated Benzimidazolium Salt Containing Spiro Structure [J].

Zeng, Wulan ;

Jiang, Jinhe .

CRYSTALS, 2017, 7 (10)

[20] Synthesis and crystal structure of Rb3AgO2 [J].

Sofin, M ;

Friese, K ;

Nuss, J ;

Peters, EM ;

Jansen, M .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2002, 628 (11) :2500-2504

← 1 2 3 4 5 →