Building Electron-Precise BoronBoron Single Bonds: Imposing Monogamy on a Promiscuous Element

被引：44

作者：

Braunschweig, Holger ^{[1
]}

Dewhurst, Rian D. ^{[1
]}

Mozo, Silvia ^{[1
]}

机构：

[1] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany

来源：

CHEMCATCHEM | 2015年 / 7卷 / 11期

基金：

欧洲研究理事会;

关键词：

boron; heterogeneous catalysis; homogeneous catalysis; hydroboration; transition metals; LEWIS-BASE ADDUCTS; B-H; BORYLENE TRANSFER; THERMAL CONDITIONS; NEUTRAL DIBORENE; CHEMISTRY; COMPLEXES; BORANE; DERIVATIVES; LIGANDS;

D O I：

10.1002/cctc.201500219

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The construction of BB bonds has recently become a major goal in synthetic chemistry owing to the intense interest in diboranes(4) as reagents for organic chemistry. Historically, synthetic methods suitable for this transformation are rare and most come with significant disadvantages. This article summarizes recent efforts by our group and others to provide new, mild, functional-group-tolerant, and convenient synthetic methods for the formation of electron-precise BB single bonds.

引用

页码：1630 / 1638

页数：9

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