Kinetics studies of sustainable biodiesel synthesis from Jatropha curcas oil by exploiting bio-waste derived CaO-based heterogeneous catalyst via microwave heating system as a green chemistry technique

被引:52
作者
Amesho, Kassian T. T. [1 ]
Lin, Yuan-Chung [1 ,2 ]
Chen, Chin-En [1 ]
Cheng, Pei-Cheng [1 ]
Shangdiar, Sumarlin [1 ]
机构
[1] Natl Sun Yat Sen Univ, Inst Environm Engn, Kaohsiung 804, Taiwan
[2] Natl Sun Yat Sen Univ, Ctr Emerging Contaminants Res, Kaohsiung 804, Taiwan
关键词
Waste oyster shells; Jatropha curcas oil; Biodiesel; Microwave heating system; Transesterification reaction; CaO-based catalyst; EGG-SHELL WASTE; CALCIUM-OXIDE; COOKING OIL; SOYBEAN OIL; PALM OIL; SUNFLOWER OIL; EDIBLE OILS; TRANSESTERIFICATION; OPTIMIZATION; METHANOLYSIS;
D O I
10.1016/j.fuel.2022.123876
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Waste oyster shells (WOS) have been progressively becoming a significant environmental issue, specifically in terms of solid waste management, which is one of the considerable barriers to the actualization of a sustainable planet. Therefore, in this present work, the CaO-based heterogeneous catalyst was developed from the recycled waste oyster shells and subsequently utilized as an efficient and excellent renewable source of the heterogeneous catalyst during the transesterification reaction of Jatropha curcas oil (JCO) for the synthesis of biodiesel. Consequently, the catalyst was prepared by calcination and characterized using different instrumental techniques, including XRD, EDS, FTIR, SEM, and BET. Under optimized conditions, the catalyst exhibited outstanding catalytic performance in converting JCO to sustainable biodiesel with a considerable yield of 91.1% under 180 min reaction time, 800 W microwave power, 65 degrees C reaction temperature, 9:1 methanol to oil ratio (MTOR), and 5 wt% catalyst loading. The reusability study revealed that WOS-derived catalyst was able to attain relatively high biodiesel yield at the first two reaction cycles, and more so, the catalyst could be potentially recycled for at least up to the 5th cycle to produce a relatively high amount of biodiesel. Furthermore, the base-catalyzed transesterification reaction was discovered to have activation energy (Ea) of 9.58 kJ/mol. The physicochemical properties of the JCO biodiesel were studied in accordance with international criterions such as ASTM and EN standards.
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页数:14
相关论文
共 88 条
[1]   Biodiesel synthesized from waste cooking oil in a continuous microwave assisted reactor reduced PM and NOx emissions [J].
Ali, Mohd Affandi Mohd ;
Gimbun, Jolius ;
Lau, Kun Lu ;
Cheng, Chin Kui ;
Vo, Dai-Viet N. ;
Lam, Su Shiung ;
Yunus, Rosli Mohd .
ENVIRONMENTAL RESEARCH, 2020, 185
[2]   Microwave-assisted combustion design of magnetic Mg-Fe spinel for MgO-based nanocatalyst used in biodiesel production: Influence of heating-approach and fuel ratio [J].
Amani, Tohid ;
Haghighi, Mohammad ;
Rahmanivahid, Behgam .
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2019, 80 :43-52
[3]   Biodiesel production from Calophyllum inophyllum oil a potential non-edible feedstock: An overview [J].
Arumugam, A. ;
Ponnusami, V. .
RENEWABLE ENERGY, 2019, 131 :459-471
[4]   Banana peduncle - A green and renewable heterogeneous base catalyst for biodiesel production from Ceiba pentandra oil [J].
Balajii, Muthusamy ;
Niju, Subramaniapillai .
RENEWABLE ENERGY, 2020, 146 :2255-2269
[5]   Utilization of renewable and sustainable basic heterogeneous catalyst from Heteropanax fragrans (Kesseru) for effective synthesis of biodiesel from Jatropha curcas oil [J].
Basumatary, Sanjay ;
Nath, Biswajit ;
Das, Bipul ;
Kalita, Pranjal ;
Basumatary, Bidangshri .
FUEL, 2021, 286
[6]   Development of a Novel Mesoporous Biocatalyst Derived from Kola Nut Pod Husk for Conversion of Kariya Seed Oil to Methyl Esters: A Case of Synthesis, Modeling and Optimization Studies [J].
Betiku, Eriola ;
Okeleye, Adebisi A. ;
Ishola, Niyi B. ;
Osunleke, Ajiboye S. ;
Ojumu, Tunde, V .
CATALYSIS LETTERS, 2019, 149 (07) :1772-1787
[7]   Utilization of waste cockle shell (Anadara granosa) in biodiesel production from palm olein: Optimization using response surface methodology [J].
Boey, Peng-Lim ;
Maniam, Gaanty Pragas ;
Hamid, Shafida Abd ;
Ali, Dafaalla Mohamed Hag .
FUEL, 2011, 90 (07) :2353-2358
[8]   In situ preparation of silver nanocomposites on cellulosic fibers - Microwave vs. conventional heating [J].
Breitwieser, Doris ;
Moghaddam, Mojtaba Mirhosseini ;
Spirk, Stefan ;
Baghbanzadeh, Mostafa ;
Pivec, Tanja ;
Fasl, Hubert ;
Ribitsch, Volker ;
Kappe, C. Oliver .
CARBOHYDRATE POLYMERS, 2013, 94 (01) :677-686
[9]  
Buasri A., 2014, APCBEE Procedia, V8, P216, DOI 10.1016/j.apcbee.2014.03.030
[10]   Biodiesel production from soybean oil and dimethyl carbonate catalyzed by potassium methoxide [J].
Celante, Dian ;
Schenkel, Joao Vitor Diel ;
de Castilhos, Fernanda .
FUEL, 2018, 212 :101-107