Competitive Adsorption at the Air-Water Interface: A Second Harmonic Generation Study

被引：15
|
作者：
Sahu, Kalyanasis [1 ,2 ]
Eisenthal, Kenneth B. [1 ]
McNeill, V. Faye [2 ]
机构：
[1] Columbia Univ, Dept Chem, New York, NY 10027 USA
[2] Columbia Univ, Dept Chem Engn, New York, NY 10027 USA
来源：
JOURNAL OF PHYSICAL CHEMISTRY C | 2011年 / 115卷 / 19期
关键词：
AIR/WATER INTERFACE; NITROGEN-DIOXIDE; AQUEOUS-SOLUTIONS; SURFACE-TENSION; HUMIC-ACID; MIXTURES; BEHAVIOR; SPECTROSCOPY; MONOLAYERS; DPPC;
D O I：
10.1021/jp2022083
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Competitive adsorption between coumarin 314 (C314) and acetonitrile at the air-water interface was studied using second harmonic generation, taking advantage of both the surface specificity and molecule selectivity of the technique. The surface concentration of C314 was selectively probed at the air-aqueous interface. As acetonitrile was added to the solution it was observed that acetonitrile displaces C314 at the interface. The experimental results are well-represented by a competitive Frumkin-Fowler-Guggenheim (cFFG) adsorption model.
引用
收藏
页码：9701 / 9705
页数：5
相关论文
共 50 条
  • [1] PalmitateLuciferin: A Molecular Design for the Second Harmonic Generation Study of Ion Complexation at the Air-Water Interface
    Martin-Gassin, Gaelle
    Arrachart, Guilhem
    Gassin, Pierre-Marie
    Lascoux, Noelle
    Russier-Antoine, Isabelle
    Jonin, Christian
    Benichou, Emmanuel
    Pellet-Rostaing, Stephane
    Diat, Olivier
    Brevet, Pierre-Francois
    JOURNAL OF PHYSICAL CHEMISTRY C, 2012, 116 (13): : 7450 - 7456
  • [2] Second harmonic generation from oxazine dyes at the air-water interface.
    Steinhurst, DA
    Owrutsky, JC
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2000, 220 : U207 - U207
  • [3] The temperature dependence of surface second- harmonic generation from the air-water interface
    Fordyce, AJ
    Bullock, WJ
    Timson, AJ
    Haslam, S
    Spencer-Smith, RD
    Alexander, A
    Frey, JG
    MOLECULAR PHYSICS, 2001, 99 (08) : 677 - 687
  • [4] Influence of the tyrosine environment on the second harmonic generation of iturinic antimicrobial lipopeptides at the air-water interface
    Nasir, Mehmet Nail
    Benichou, Emmanuel
    Loison, Claire
    Russier-Antoine, Isabelle
    Besson, Francoise
    Brevet, Pierre-Francois
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2013, 15 (45) : 19919 - 19924
  • [5] Molecular organization and phase transition at the air-water interface investigated by second-harmonic generation
    Benichou, Emmanuel
    Bruyere, Aurelie
    Forel, Emilie
    Bonhomme, Oriane
    Brevet, Pierre-Francois
    ORGANIC PHOTONIC MATERIALS AND DEVICES XVII, 2015, 9360
  • [6] Neutron reflectivity study of competitive adsorption of β-lactoglobulin and nonionic surfactant at the air-water interface
    Horne, DS
    Atkinson, PJ
    Dickinson, E
    Pinfield, VJ
    Richardson, RM
    INTERNATIONAL DAIRY JOURNAL, 1998, 8 (02) : 73 - 77
  • [7] Orientational order study of monolayers at the air-water interface by Maxwell-displacement current and optical second harmonic generation
    Tojima, A
    Manaka, T
    Iwamoto, M
    JOURNAL OF CHEMICAL PHYSICS, 2001, 115 (19): : 9010 - 9017
  • [8] Compression induced chirality in dense molecular films at the air-water interface probed by second harmonic generation
    Martin-Gassin, G.
    Benichou, E.
    Bachelier, G.
    Russier-Antoine, I.
    Jonin, Ch.
    Brevet, P. F.
    JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (33): : 12958 - 12965
  • [9] Adsorption of actin at the air-water interface:: A monolayer study
    Gicquaud, C
    Chauvet, JP
    Grenier, G
    Tancrède, P
    Coulombe, G
    BIOPOLYMERS, 2003, 70 (03) : 289 - 296
  • [10] Chirality of citronelloxy-cyanobiphenyl monolayer at the air-water interface investigated by the second harmonic generation measurement
    Manaka, Takaaki
    Tamura, Ryosuke
    Iwamoto, Mitsumasa
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2006, 284 : 409 - 413
12345