Ferromagnetic coupling mediated by Co•••π non-covalent contacts in a pentacoordinate Co(II) compound showing field-induced slow relaxation of magnetization

被引：23

作者：

Nemec, I. ^{[1
]}

Herchel, R. ^{[1
]}

Travnicek, Z. ^{[1
]}

机构：

[1] Palacky Univ, Fac Sci, Dept Inorgan Chem, Reg Ctr Adv Technol & Mat, 17 Listopadu 12, CZ-77146 Olomouc, Czech Republic

来源：

DALTON TRANSACTIONS | 2016年 / 45卷 / 31期

关键词：

THIOCYANATE ANIONS; COMPLEXES; LIGANDS; ANISOTROPY; CRYSTAL;

D O I：

10.1039/c6dt01539e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[Co-II(dpt)(NCS)(2)], where dpt = bis(3-aminopropyl)amine, was identified as a pentacoordinate Co-II compound showing field-induced slow relaxation of magnetization. Furthermore, intermolecular ferromagnetic coupling mediated by Co center dot center dot center dot pi non-covalent contacts, where pi orbitals originate from the thiocyanato ligand, is reported for the first time.

引用

页码：12479 / 12482

页数：4

共 19 条

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