A general halide-to-anion switch for imidazolium-based ionic liquids and oligocationic systems using anion exchange resins (A- form)

被引:24
作者
Alcalde, Ermitas [1 ]
Dinares, Immaculada [1 ]
Ibanez, Anna [1 ]
Mesquida, Neus [1 ]
机构
[1] Univ Barcelona, Fac Farm, Lab Quim Organ, E-08028 Barcelona, Spain
关键词
AZOLATE INNER SALTS; HETEROCYCLIC BETAINES; REACTIVITY; RECEPTORS; EVOLUTION;
D O I
10.1039/c0cc05350c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Further studies on the application of an AER (A(-) form) method broadened the anion exchange scope of representative ionic liquids and bis(imidazolium) systems. Depending on the hydrophobicity nature of the targeted imidazolium species and counter-anions, different organic solvents were used to swap halides for assorted anions, proceeding in excellent to quantitative yields.
引用
收藏
页码:3266 / 3268
页数:3
相关论文
共 39 条
[1]   Tunable Aryl Alkyl Ionic Liquids (TAAILs): The Next Generation of Ionic Liquids [J].
Ahrens, Sebastian ;
Peritz, Anke ;
Strassner, Thomas .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (42) :7908-7910
[2]   Heterocyclic betaines. 30. A direct synthetic approach to novel quadrupolar [1(4)]azolophanes [J].
Alcade, E ;
Alemany, M ;
Gisbert, M .
TETRAHEDRON, 1996, 52 (48) :15171-15188
[3]   AZINIUM AZOLATE INNER SALTS - SYNTHESIS AND STRUCTURAL STUDIES [J].
ALCALDE, E ;
DINARES, I ;
ELGUERO, J ;
FAYET, JP ;
VERTUT, MC ;
MIRAVITLLES, C ;
MOLINS, E .
JOURNAL OF ORGANIC CHEMISTRY, 1987, 52 (22) :5009-5015
[4]   HETEROCYCLIC BETAINES - AZA ANALOGS OF SESQUIFULVALENE .2. AZOLIUM AZOLATE INNER SALTS - SYNTHESIS, REACTIVITY, AND STRUCTURE OF A 1-1 ADDUCT WITH DIMETHYL ACETYLENEDICARBOXYLATE [J].
ALCALDE, E ;
DINARES, I .
JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (13) :4233-4238
[5]  
ALCALDE E, 1995, CHEM COMMUN, P1239
[6]   Imidazolium-based dicationic cyclophanes.: Solid-state aggregates with unconventional (C-H)+•••Cl- hydrogen bonding revealed by X-ray diffraction [J].
Alcalde, Ermitas ;
Mesquida, Neus ;
Vilaseca, Marta ;
Alvarez-Rua, Carmen ;
Garcia-Granda, Santiago .
SUPRAMOLECULAR CHEMISTRY, 2007, 19 (07) :501-509
[7]   Anion receptor chemistry: highlights from 2007 [J].
Caltagirone, Claudia ;
Gale, Philip A. .
CHEMICAL SOCIETY REVIEWS, 2009, 38 (02) :520-563
[8]   Reactivity of ionic liquids [J].
Chowdhury, Shahana ;
Mohan, Ram S. ;
Scott, Janet L. .
TETRAHEDRON, 2007, 63 (11) :2363-2389
[9]   Synthesis, Purification and Characterization of Ionic Liquids [J].
Clare, Bronya ;
Sirwardana, Amal ;
MacFarlane, Douglas R. .
IONIC LIQUIDS, 2009, 290 :1-40
[10]   Assessing the greenness of some typical laboratory ionic liquid preparations [J].
Deetlefs, Maggel ;
Seddon, Kenneth R. .
GREEN CHEMISTRY, 2010, 12 (01) :17-30