p-(Benzyloxy)calix[8]arene Synthesis Revisited: p-(Benzyloxy)calix[4]-, p-(Benzyloxy)calix[5]-, p-(Benzyloxy)calix[7]-, and p-(Benzyloxy)bis(homooxa)calix[4]arenes

被引：6
|
作者：
Huc, Vincent [1 ]
Npetgat, Eloine [1 ]
Guerineau, Vincent [2 ]
Bourcier, Sophie [3 ]
Dos Santos, Amandine [1 ]
Guillot, Regis [1 ]
Baltaze, Jean-Pierre [1 ]
Martini, Cyril [1 ]
机构：
[1] Univ Paris Sud, Inst Chim Mol & Mat Orsay, F-91405 Orsay, France
[2] CNRS, Inst Chim Subst Nat, F-91198 Gif Sur Yvette, France
[3] Ecole Polytech, DCMR, F-91128 Palaiseau, France
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2010年 / 2010卷 / 32期
关键词：
Calixarenes; Alkylation; Functionalization; Supramolecular chemistry; CRYSTAL-STRUCTURE; MOLECULAR RECOGNITION; CALIXARENES; NANOPARTICLES; ION; COORDINATION; DERIVATIVES; CHEMISTRY; COMPLEX; LIGAND;
D O I：
10.1002/ejoc.200901405
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A detailed investigation of the 4-(benzyloxy)phenol/formal-dehyde reaction shows that along with the previously described p-(benzyloxy)calix[8]arene and p-(benzyloxy)calix[6]arene, others calixarenes are observed and easily recovered on a preparative scale. All these new calixarenes are opening interesting perspectives for the synthesis of new supramolecular hosts, easily functionalized at the para position under very mild conditions and/or exhibiting a deep hydrophobic pocket.
引用
收藏
页码：6186 / 6192
页数：7
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