Humic acid fouling in a submerged photocatalytic membrane reactor with binary TiO2-ZrO2 particles

被引:40
作者
Khan, Sovann [1 ,2 ,3 ]
Kim, Jeonghwan [3 ]
Sotto, Arcadio [4 ]
Van der Bruggen, Bart [5 ]
机构
[1] Korea Inst Sci & Technol, Ctr Mat Architecturing, Seoul 136791, South Korea
[2] Korea Univ Sci & Technol, Dept Nanomat Sci & Engn, Taejon, South Korea
[3] Inha Univ, Dept Environm Engn, Inchon, South Korea
[4] Rey Juan Carlos Univ, Dept Chem & Environm Technol, Madrid 28933, Spain
[5] Katholieke Univ Leuven, Dept Chem Engn, B-3001 Leuven, Belgium
基金
新加坡国家研究基金会;
关键词
TiO2/ZrO2 composite oxide; Photocatalytic membrane reactor; Membrane fouling; Humic acid; NATURAL ORGANIC-MATTER; WATER TREATMENT; METAL-OXIDES; TIO2; NANOPARTICLES; DEGRADATION; OXIDATION; BEHAVIOR; REMOVAL; SURFACE;
D O I
10.1016/j.jiec.2014.04.012
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The binary TiO2-ZrO2 particles were better alternative to TiO2 particles as photocatalyst to reduce humic acid fouling in photocatalytic membrane reactor. The structure of the TiO2-ZrO2 particles was strongly dependent upon the content of zirconium as an additive. A composition of 50% TiO2 with 50% ZrO2 was optimal in terms of physicochemical properties. The effect of TiO2-ZrO2 particles on the reduction of humic acid fouling was further improved by the presence of divalent cations such as calcium. Nevertheless, the stability of polymeric membranes in longer-term operation using a hybrid photocatalytic membrane reactor for water treatment applications may remain a challenge. (C) 2014 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:779 / 786
页数:8
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