Modeling of Au Chlorination Leaching Kinetics from Copper Anode Slime

被引:7
作者
Saeedi, Molood [1 ]
Sadeghi, Nima [1 ]
Alamdari, Eskandar Keshavarz [1 ]
机构
[1] Amirkabir Univ Technol, Tehran Polytech, Dept Mat & Met Engn, Tehran, Iran
关键词
Chlorination leaching; Gold; Copper anode slime; Leaching kinetics; PILOT-PLANT SCALE; TRIBUTYL-PHOSPHATE; GOLD; EXTRACTION; RECOVERY; DISSOLUTION; SILVER;
D O I
10.1007/s42461-021-00482-z
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
This study showed the kinetics of gold chlorination leaching from an anode slime complex containing copper, silver, barium, selenium, and tellurium. AgCl and BaSO4 control the rate of gold leaching, and the interface transfer and diffusion across the product was selected as the desirable kinetic model. The concentration of hydrochloric acid, chlorine gas flow rate, pulp density, and temperature have been precisely studied. The results showed that temperature and hydrochloric acid have a favorable influence on the leaching rate. However, the chlorine gas flow rate is inactive in the reaction rate. Furthermore, the leaching rate decreased with an increasing pulp density. The leaching process was controlled by the interface transfer and diffusion across the product, and the activation energy was determined to be 13.66 kJ mol(-1).
引用
收藏
页码:2559 / 2568
页数:10
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