Mechanochemical Ruthenium-Catalyzed Olefin Metathesis

被引：131

作者：

Do, Jean-Louis ^{[1
]}

Mottillo, Cristina ^{[1
]}

Tan, Davin ^{[1
]}

Strukil, Vjekoslav ^{[1
]}

Friscic, Tomislav ^{[1
]}

机构：

[1] McGill Univ, Dept Chem, FRQNT Ctr Green Chem & Catalysis, Montreal, PQ H3A 2K6, Canada

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2015年 / 137卷 / 07期

基金：

加拿大创新基金会; 加拿大自然科学与工程研究理事会;

关键词：

SOLVENT-FREE SYNTHESIS; COUPLING REACTIONS; CROSS-METATHESIS; TERMINAL ALKYNES; SCALE-UP; IN-SITU; DERIVATIVES; MECHANOSYNTHESIS; TRANSFORMATION; ACTIVATION;

D O I：

10.1021/jacs.5b00151

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We describe the development of a mechanochemical approach for Ru-catalyzed olefin metathesis, including cross-metathesis and ring-closing metathesis. The method uses commercially available catalysts to achieve high-yielding, rapid, room-temperature metathesis of solid or liquid olefins on a multigram scale using either no or only a catalytic amount of a liquid.

引用

页码：2476 / 2479

页数：4

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