Mechanochemical Ruthenium-Catalyzed Olefin Metathesis

被引：131

作者：

Do, Jean-Louis ^{[1
]}

Mottillo, Cristina ^{[1
]}

Tan, Davin ^{[1
]}

Strukil, Vjekoslav ^{[1
]}

Friscic, Tomislav ^{[1
]}

机构：

[1] McGill Univ, Dept Chem, FRQNT Ctr Green Chem & Catalysis, Montreal, PQ H3A 2K6, Canada

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2015年 / 137卷 / 07期

基金：

加拿大自然科学与工程研究理事会; 加拿大创新基金会;

关键词：

SOLVENT-FREE SYNTHESIS; COUPLING REACTIONS; CROSS-METATHESIS; TERMINAL ALKYNES; SCALE-UP; IN-SITU; DERIVATIVES; MECHANOSYNTHESIS; TRANSFORMATION; ACTIVATION;

D O I：

10.1021/jacs.5b00151

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We describe the development of a mechanochemical approach for Ru-catalyzed olefin metathesis, including cross-metathesis and ring-closing metathesis. The method uses commercially available catalysts to achieve high-yielding, rapid, room-temperature metathesis of solid or liquid olefins on a multigram scale using either no or only a catalytic amount of a liquid.

引用

页码：2476 / 2479

页数：4

共 87 条

[71] Solvent-Free Cross-Dehydrogenative Coupling Reactions under High Speed Ball-Milling Conditions Applied to the Synthesis of Functionalized Tetrahydroisoquinolines
Su, Weike
Yu, Jingbo
Li, Zhenhua
Jiang, Zhijiang
[J]. JOURNAL OF ORGANIC CHEMISTRY, 2011, 76 (21) : 9144 - 9150
[72] Mechanochemistry and sonochemistry: concluding remarks
Suslick, Kenneth S.
[J]. FARADAY DISCUSSIONS, 2014, 170 : 411 - 422
[73] Development of C-N Coupling Using Mechanochemistry: Catalytic Coupling of Arylsulfonamides and Carbodiimides
Tan, Davin
Mottillo, Cristina
Katsenis, Athanassios D.
Strukil, Vjekoslav
Friscic, Tomislav
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (35) : 9321 - 9324
[74] Mechanosynthesis of pharmaceutically relevant sulfonyl-(thio)ureas
Tan, Davin
Strukil, Vjekoslav
Mottillo, Cristina
Friscic, Tomislav
[J]. CHEMICAL COMMUNICATIONS, 2014, 50 (40) : 5248 - 5250
[75] Fast, ligand- and solvent-free copper-catalyzed click reactions in a ball mill
Thorwirth, Rico
Stolle, Achim
Ondruschka, Bernd
Wild, Andreas
Schubert, Ulrich S.
[J]. CHEMICAL COMMUNICATIONS, 2011, 47 (15) : 4370 - 4372
[76] Fast copper-, ligand- and solvent-free Sonogashira coupling in a ball mill
Thorwirth, Rico
Stolle, Achim
Ondruschka, Bernd
[J]. GREEN CHEMISTRY, 2010, 12 (06) : 985 - 991
[77] Olefin metathesis in aqueous media
Tomasek, Jasmine
Schatz, Juergen
[J]. GREEN CHEMISTRY, 2013, 15 (09) : 2317 - 2338
[78] Selective polymorph transformation via solvent-drop grinding
Trask, AV
Shan, N
Motherwell, WDS
Jones, W
Feng, SH
Tan, RBH
Carpenter, KJ
[J]. CHEMICAL COMMUNICATIONS, 2005, (07) : 880 - 882
[79] N-heterocyclic carbene transition metal complexes for catalysis in aqueous media
Velazquez, Heriberto Diaz
Verpoort, Francis
[J]. CHEMICAL SOCIETY REVIEWS, 2012, 41 (21) : 7032 - 7060
[80] Removing Ruthenium Residues from Olefin Metathesis Reaction Products
Vougioukalakis, Georgios C.
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2012, 18 (29) : 8868 - 8880

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