Assemblies of covalently cross-linked nanosheets of MoS2 and of MoS2-RGO: synthesis and novel properties

被引:49
作者
Pramoda, K. [1 ]
Gupta, Uttam [1 ]
Ahmad, Irshad [1 ]
Kumar, Ram [1 ]
Rao, C. N. R. [1 ]
机构
[1] Jawaharlal Nehru Ctr Adv Sci Res, New Chem Unit, Chem & Phys Mat, Unit CSIR Ctr Excellence Chem,Sheikh Saqr Lab, Jakkur PO, Bangalore 56006, Karnataka, India
关键词
TRANSITION-METAL DICHALCOGENIDES; HYDROGEN EVOLUTION; COORDINATION; EFFICIENT; GRAPHENE; FUNCTIONALIZATION; NANOCOMPOSITE; NANOMATERIALS; IODOBENZENE; ADSORPTION;
D O I
10.1039/c6ta00645k
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We report the synthesis, characterization, gas adsorption and hydrogen evolution activity of covalently cross-linked assemblies of MoS2 and MoS2-RGO generated by the Sonogashira coupling reaction. These assemblies show a high surface area and CO2 storage capacity comparable with some of the high surface area MOFs. MoS2 assemblies show enhanced hydrogen evolution activity compared to few-layer MoS2.
引用
收藏
页码:8989 / 8994
页数:6
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